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Absorbance additivity

The more highly complexed hydrates of calcium chloride (CaCl2 nH2 O where n > 2) may also exhibit the characteristics of a Class 2 dryiag agent, because the hydrated species can physically absorb additional water to form a saturated solution. The term absorption is used to describe the phenomenon that occurs when a gas or vapor penetrates the soHd stmcture to produce a saturated solution ... [Pg.506]

In previous sections, it has been assumed that all energy within a pressure vessel is available to drive the blast wave. In fact, energy must be spent to rupture the vessel and propel its fragments. In some cases, the vessel expands before bursting, thus absorbing additional energy. Should a vessel also contain liquid or solids, a fraction of the available energy may be spent in its propulsion. [Pg.198]

High compatibility of the additive with the polymer matrix usually extends performance but at the expense of extractability. Lack of extractability is of analytical concern, e.g. in case of functionalised oligomer and polymeric additives, grafted and reactive additive functionalities, and chemisorbed and absorbed additives. More generally, additive recovery levels significantly lower than the target level may arise from various situations ... [Pg.141]

Coleman et al. 2471 reported the spectra of different proportions of poly(vinylidene fluoride) PVDF and atactic poly(methyl methacrylate) PMMA. At a level of 75/25 PVDF/PMMA the blend is incompatible and the spectra of the blend can be synthesized by addition of the spectra of the pure components in the appropriate amounts. On the other hand, a blend composition of 39 61 had an infrared spectrum which could not be approximated by absorbance addition of the two pure spectra. A carbonyl band at 1718cm-1 was observed and indicates a distinct interaction involving the carbonyl groups. The spectra of the PVDF shows that a conformational change has been induced in the compatible blend but only a fraction of the PVDF is involved in the conformational change. Allara M9 250 251) cautioned that some of these spectroscopic effects in polymer blends may arise from dispersion effects in the difference spectra rather than chemical effects. Refractive index differences between the pure component and the blend can alter the band shapes and lead to frequency shifts to lower frequencies and in general the frequency shifts are to lower frequencies. [Pg.131]

The nodules are formed by the oxidation and precipitation of iron and manganese. The oxidation of Mn24 is catalyzed by a reaction surface io a tetravalent state that absorbs additional Fe2+ or Mn2+ which, in turn, becomes oxidized. A surface is required and the initial deposition may be of iron oxide, possibly from volcanic or geothermal sources. Proper conditions of pH, redox potential, and metal ion concentration are found in deep ocean waters. The rate of accumulation appears to be very slow. The growth also may be discontinuous, and is estimated at a faster rater rate near the continental margins. [Pg.1131]

Harvest Period. Wang reported also (2) that bamboo should be harvested from late summer to mid-autumn because the natural moisture content of the bamboo is lowest then. Since the bamboo has not absorbed additional moisture from the ground, the swelling and shrinkage characteristics in the bamboo culm are at a minimum. [Pg.255]


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