2H-Pyran

J-Pyran-2-acetamid, Ai-[[6-(2,3-dimethoxypropyl)tetrahydro-4-hydroxy-5,5-dimethyl-2H-pyran-2-yl]rriethoxymethyl]tetrahydro-a-hydroxy-2-methoxy-5,6-dimethyl-4-rTiethylene]-... 

Intermediates. 3,4-Dihydro-2H-pyran [110-87-2] is prepared by a ring-expanding dehydration of tetrahydrofurfuryl alcohol. It is used as a protecting agent for hydroxyl compounds and as an intermediate. 2-Methylfuran is a chemical intermediate for 5-methylfurfural [620-02-0] (151) and... 

Penicillin V—see Penicillin, phenoxymethyl-, 7, 300 Penicilloate, benzyl-, 7, 303 Penicilloate, D-a-benzyl-a-methyl ester, 7, 303 Penillamine, benzyl-, 7, 303 Penillic acid, benzyl-, 7, 303 Penilloaldehyde, benzyl-, 7, 303 Penilloic acid, benzyl-, 7, 303 Penillonic acid, benzyl-methyl ester, 7, 303 1,2,3,4,6-Pentaazaindene nomenclature, 1, 18 Pentadeca-5,10-dienols synthesis, 1, 428 Pentadienol, tetrachloro-2H-pyran synthesis from, 3, 740 Pentadienonitrile, 5-(l,2-benzoselenazol-3-yl)-X-ray diffraction, 6, 334 Penta-2,4-dienonitrile, 5-(dimethylamino)-2-(2-thienyl)-... 

UV spectra, S, 844 Pent-2-ene, perfluoro-2-methyl-2H-pyran synthesis from, 3, 740 Pent-2-enedioic acid, 2,4-diacetyl-esters... 

H-Pyran, 4-alkyl-5,6-dihydro-conformation, 3, 630 2H-Pyran, 5-alkyl-2-ethoxy-3,4-dihydro-reactions... 

H-Pyran, 3,4-dihydro-2-methoxy-4-methyl-synthesis, 3, 772 2H-Pyran, dimethoxy-reactions... 

H-Pyran, 2-hydroxy-2,4,6-triphenyl-IR spectra, 3, 593 2H-Pyran, 2-methoxy-synthesis, 3, 741... 

H-Pyran-6-carboxylic acid, rrans-2-alkoxy-5,6-dihydro- H NMR,3, 578 Pyrancarboxylic acids, oxo-decarboxylation, 2, 52 Pyran-5-carboxylic acids synthesis, 3, 792... 

Similar cycloaddition reactions were observed with methyl vinyl sulfone (48) and )3-nitrostyrene (48,51). Methyl vinyl ketone, on the other hand, is reported to give dihydropyrans as the initial products (50,52,53). Thus (16) on reaction with methyl vinyl ketone at room temperature for 12 hr gave a 60% yield of 2-dimethylamino-3,3,6-trimethyl-3,4-dihydro-2H-pyran (59). 

Dimethyl[1,1 -dimethyl-3-(tetrahydro-2H-pyran-2-yloxy)propylsilyl, 657... 

A 2,4)6-trisubstituted 2H or 4/f) pyran (38, R = R = Ph) was reported to result in low yield by catalytic reduction of 2,4,6-triphenyl-pyrylium salts by oxidation or by treatment with concentrated sulfuric acid it regenerated the triphenylpyrylium cation. There was no subsequent confirmation of this reaction. The reduction of pyrylium salts with sodium borohydride affords 1,5-diones by way of 4H-pyrans and 2,4-dien-l-ones by way of 2H-pyrans. ... 

Still another possibility of isomerization is illustrated by the easy interconversions between pentaphenylpentadienoie aeid chloride and 2-chloropentaphenyl-3-eyelopenten-l-one. Interestingly, 2,4,6-trimethylpjrrylium iodide maj be sublimed without decomposition in a vacuum, possibly as a covalent 6-iodo-4-methyl-3,5-heptadien-2-one or 2-iodo-2,4,6-trimethyl-2H-pyran valenee isomer. In a related case, chlorocyclopropenes are covalent and are converted into cyclo-propenium derivatives only by the action of Friedel-Crafts catalysts (electron-deficient metallic chlorides) (ef. also Section II,C, 2,c.)... 

---