Zoning, gasifier

SL/RN Process. In the SL/RN process (Fig. 4), sized iron ore, coal, and dolomite are fed to the rotary kiln wherein the coal is gasified and the iron ore is reduced. The endothermic heat of reduction and the sensible energy that is required to heat the reactants is provided by combustion of volatiles and carbon monoxide leaving the bed with air introduced into the free space above the bed. The temperature profile in the kiln is controlled by radial air ports in the preheat zone and axial air ports in the reduction zone. Part of the coal is injected through the centerline of the kiln at the discharge end. The hot reduced iron and char is discharged into an indirect rotary dmm cooler. The cooled product is screened and magnetically separated to remove char and ash. 

The importance of these concepts can be illustrated by the extent to which the pyrolysis reactions contribute to gas produdion. In a moving-bed gasifier (e.g., producer-gas gasifier), the particle is heated through several distinct thermal zones. At the initial heat-up zone, coal carbonization or devolatilization dominates. In the successively hotter zones, char devolatihzation, char gasification, and fixed carbon... 

It has been postulated that CH4 in the gaseous form or dissolved in water enters into root aerenchyma, which forms by degeneration of cortical cells between the exodermis and the vascular bundle, where the dissolved CH4 is gasified and moves by diffusion from the root aerenchyma through the restrictive transition zone into the aerenchyma of the culm and then... 

Kojima, T., Yoshitake, H., Kimura, T., Matsukata, M., and Uemiya, S., Contribution of Local Reactions in the Grid Zone to the Performance of a Jetting Fluidized Bed Gasifier of Coal Char, Energy Fuels, 9 379 (1995)... 

With fixed-bed updraft gasifiers, the air or oxygen passes upward through a hot reactive zone near the bottom of the gasifier in a direction countercurrent to the flow of solid material. Exothermic reactions between air/oxygen and the... 

Most tars in the product gas are destroyed by thermal cracking as they pass through the hot reaction zone, and the raw product then exits the gasifier at high temperature. The particulate levels in the product gas are typically low due to the absence of turbulence in the gasifier, but the gas may contain alkali vapors as it exits the hot reaction zone. 

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