Wohl

W2) Wobl Equation of State. It is the 4th degree in the volume virial equation proposed in 1914 by Wohl and described in Addnl Ref Aj. it was used by Joffe (Ref 2a) far calcn of parameters of some gases in order to compare the results with those obtd by using the eq (5) of Joffe with equation of Beattie-Bridgeman and vanderWaals Joffe gives (Ref 2a, p 541) for Wohl equation  

Vol 1 (1946), Chapter 5, The Theory of Detonation Process (Based on Summary by S.R. Brinkley, Jr) lh) G.J. Su C.H. Chang, JACS 68, 1080-83 (1946) (Equation of state for real gases) li) Ibid, IEC 38, 800-02 802-03(1946) (Equations of state for real gases) lj) M.A. Cook, jChemPhys 15, 518-24(1947 (An equation of state at extremely high temperatures and pressures from the hydrodynamic theory of detonation) 

JACS 69, 540-42(1947) (A new equation of state for gases) 2b) Ibid, 69, 1216-17(1947) (A modification of Dieterici equation of state) 2c) G. Morris H. Thomas, Research (London), 1, 132-44(1947) (Equations of state) 2d) S. Paterson, Ibid, 1, 221(1948) (Equation of state) 2e) M.A. Cook, JChemPhys 16, 554-55 (1948) (An equation of state at extremely high temperature from hydrodynamic theory of detonation) 

Wentorf et al, JChemPhys 18, 1484-1500(1950) (Lennard-Jones and Devonshire equation of state of compressed gases and liquids) 3) S.G. Starling A.J. Woodall, Physics , Longmans-Green, London(1950), 264 273 3a) S. Travers, MAF 24, 443- 

Cottrell S. Paterson, PrRoySoc 213 A, 214-15(1952) (An equation of state applicable to gases at high densities and high temperatures 7b) J.E. Mayer G. Careri, JChemPhys 20, 1001(1952) (An equation of state based on intermolecular potentials) 8) VanNostrand s Diet (1953), pp indicated in the text 8a) M.P. Murgai, ProcNatllnstScilndia 19, 541-45(1953)  

---

The direct introduction of a halogen atom (usually bromine) by means of V-haloamine (generally iV-bromosuccinimide) in the allyl position is known as the Wohl-Ziegler reaction ... 

Williamson synthesis Wohl-Ziegler reaction Wolff rearrangement Wolff Kishner reduction Wurtz reaction Wurtz-Fittig reaction... 

Wohl-Aue synthesis Wohlwill process Wolff-Chaikoff effect... 

Many substituted quinolines are intermediates for antimalarials. The 2,4-di-substituted quinolines are produced from aniline and 1,3-diketones by the Combes quinoline synthesis (28). The reaction of aniline with nitrobenzene in the presence of dry sodium hydroxide at 140°C leads to formation of phenazine [92-82-0] and by-products (Wohl-Aue synthesis) (29). 

WOHL - WEYGAND Aldose degradation Degradation of sugar oximes via cyanohydrins by means of an acid chloride/pyridine (Wohl) or of... 

Satisfactory methods for the preparation of acrolein have been described by Wohl and Mylo,i Witzemann, andMoureu. In the Wohl and Mylo method the vapors of glycerol are passed over magnesium sulfate maintained at 330-340.° Witzemann s method involves the use of magnesium sulfate at elevated temperatures with the consequent danger of breaking the generating flasks. Moureu s method involves apparatus not always available. 

The shock-induced micromechanical response of <100>-loaded single crystal copper is investigated [18] for values of (WohL) from 0 to 10. The latter value results in W 10 Wg at y = 0.01. No distinction is made between total and mobile dislocation densities. These calculations show that rapid dislocation multiplication behind the elastic shock front results in a decrease in longitudinal stress, which is communicated to the shock front by nonlinear elastic effects [pc,/po > V, (7.20)]. While this is an important result, later recovery experiments by Vorthman and Duvall [19] show that shock compression does not result in a significant increase in residual dislocation density in LiF. Hence, the micromechanical interpretation of precursor decay provided by Herrmann et al. [18] remains unresolved with existing recovery experiments. 

The first example (49) was obtained by Wohl in 1901 by reacting an aqueous solution of oxalic acid with the diethyl acetal of y-benzoylaminopropionaldehyde. 

Olefins react with bromine by addition of the latter to the carbon-carbon double bond. In contrast the Wohl-Ziegler bromination reaction using N-bromosuccinimide (NBS) permits the selective substitution of an allylic hydrogen of an olefinic substrate 1 by a bromine atom to yield an allylic bromide 2. 

---