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Why does adding salt remove a blood stain

Why does adding salt remove a blood stain  [Pg.462]

Haemoglobin is an essential component of the blood. The central, active part of the molecule comprises a haem ring (as above) at the centre of which lies an iron ion. We call it a charge transfer couple, since it requires two constituents, both the iron and the haem. [Pg.462]

An old-fashioned way of removing the stain caused by blood is to place the stained item in a fairly concentrated solution of salt, and is usually performed by sprinkling table salt on the bloodied cloth after dampening it under a tap. [Pg.462]

After a while, sodium ions from the salt swap for the iron ion at the centre of the haem ring. There is no longer a couple (one component is lost), and consequently no scope for an MLCT transition, so the red colour of the blood fades. [Pg.462]

It is likely that the haem remains incorporated in the cloth, but it is not involved in a charge-transfer type of process and is now invisible. [Pg.462]




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