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Vanadium complexes ligand exchange

GL Rice, SL Scott. Characterization of silica-supported vanadium(V) complexes derived from molecular precursors and their ligand exchange reactions. Langmuir 13 1545-1551,1997. [Pg.544]

All three oxidation states of vanadium found in living systems form stable complexes with a wide variety of mono- and multidentate ligands. Ions of these three oxidation states form complexes rapidly they are therefore labile. As mentioned on page 142, bimolecular complex formation rate constants for monomeric vanadate species are approximately 104 M V1. Water exchange rate constants are 280s 1 for V3+, and 500s 1 for V02+ at 25 °C52. ... [Pg.149]

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See also in sourсe #XX -- [ Pg.62 ]



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