Van der Waals stabilization

Thus the van der Waals stabilization should be maximized in the P3/2 3/2 state by allowing the rare gas atoms above and below the xy plane to approach the metal atom more closely than those lying in the xy plane. In terms of the substitutional site, this corresponds to an axial contraction along the z-axis, which... 

Binding of the guest molecule to the cavity is accompanied by van der Waals stabilization (H dw), which is calculated by using Hill s potential (52). Freedom of one-dimensional rotation is assumed to be allowed for the inclusion complex (S ol(1.D)). 

Hydrogen bonds and intramolecular interactions (electrostatic, van der Waals) stabilize the native structure of the protein in a co-operative manner. Upon denaturation, the co-operative effect is lost, resulting in tmfolding of the molecule and exposure of the inner hydrophobic core to the hydrophilic aqueous environment. For small globular proteins, denaturation is an almost all-or-none... 

The formation of 208sf as the major coupling product of 8 and 209 was an unexpected observation and consequently reasons were sought for such a predominance. An energy minimization carried out on v and 208sf indicated that the self-filled conformer enjoys a van der Waals stabilization energy of... 

The primary concept for aromatie-aromatic interactions is nondirectional van der Waals stabilization, enhanced by 7t-polarizability, plus electrostatic stabilization that is directional. This concept needs to be expanded, beeause there are additional sources of stabilization. Where two aromatie molecules have different electron affinities, sueh that there is a complementary relation-... 

Zhang, F., Baralia, G.G., Nysten, B., Jonas, A.M. Melting and van der Waals stabilization of PE single crystals grown from ultrathin films. Mactomolecules 44(19), 7752—7757 (2011)... 

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