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Use of a Trithioester Transfer Agent

This trithiocarbonate is expected to exhibit high chain transfer efficiency and good control over the RAFT because the living group corres- [Pg.74]

Finally, Convertine et al. [199] illustrated the use of S,S,-bis(o c/-dimclhyl-acetic acid)trithiocarbonate for the RAFT of both acrylamide and N,N- [Pg.75]

This first pathway using a trithioester transfer agent afforded functionality close to 2. However, the final oligomer contains a trithioester group in the middle of the chain that is highly labile. A further polycondensation, which requires high temperature, with such oligomers, obtained by this technique, seems not to be favored. [Pg.76]


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Trithioester transfer agent

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