Tungsten trichloro

C1C2Hj, Acetic acid, chloro-ruthenium complex, 26 256 02C1,WC,Hi, Tungsten(VI), trichloro(l,2-dimethoxyethane)(2,2-dimethylpro-pylidyne)-, 26 50... 

Tungsten(VI) fluoride is a colorless liquid with bp 17.5 °C (mp 2.3 °C) and density 3.44. It is soluble in l,l,2-trichloro-l,2,2-trifluoroethane (Freon 113), diehloromethane, and chloroform. It does not react18 with carbon disulfide, and with ethers only at elevated temperatures.9... 

In addition to the reagents described, NC13 has been reported to generate trichloro-tungsten nitride 105 from the corresponding tungsten hexacarbonyl 104 (Eq. (39)). 

WC1)NP2C 2H32, Tungsten(V), trichloro-(phenylimido)bis(trimethylphosphine)-, 24 196... 

Trichloro(tripyridine)chromium(III), synthesis 36 Tris(3-bromoacetylacetonato)chromium(III), synthesis 37 Cyclopentadienyl tricarbonyl hydrides of chromium, molybdenum, and tungsten, synthesis 38 Trichloro(tripyridine)molybdenum(III), synthesis 39 Potassium octacyanotungstate(IV) 2-hydrate, synthesis 40 Chlorine(CP )-labeled thionyl chloride, silicon tetrachloride, boron chloride, germanium (IV) chloride and phosphorus(III) chloride, synthesis 44 Unipositive halogen complexes, synthesis 46 Monopyridineiodine(I) chloride, synthesis 47 Manganese(III) acetylacetonate, synthesis 49 Triiron dodecacarbonyl, synthesis 52... 

OBHIN7WC18H24, Tungsten(II), (acetonitrile-K A, C)carbonyliodo[tris-(3,5-dimethylpyr-azolyl)hydroborato]-, 33 226 OCl2NPtSC4H9, Platinum(II), dichloro(acetoni-trile)(dimethylsulfoxide)-, cis-, 33 192 OCl3KPtSC2H5, Platinate(II), trichloro(di-methylsulfoxide)-, potassium, 33 191 OCl6Fe2N2Ci6H4o, Ferrate(3-), /i-oxo-hexa-chlorodi-, bis(tetraethylammonium),... 

Internal proton transfer is observed for amido ligands. The reaction between the 1,2-dimethoxyethane adduct of trichloro(carbyne)molybdenum or -tungsten complexes and (trimethylsilyl)aiylamines produces the stable intermediates 20. The latter, however, re-... 

Addition of one equivalent of an internal allqtne, trichloro(l,2-dimethoxyethane-0,0 )-(2,2-dimethylpropylidyne)tungsten(VI) affords a stable tungstacyclobutadiene product, but reaction with additional alkyne yields q -cyclopentadienyl products of further alkyne insertion rather than products of allcyne metathesis.l l... 

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