Troposphere global

While the Henry s law constant for ozone is fairly small (Table 8.1), there is sufficient ozone present in the troposphere globally to dissolve in clouds and fogs, hence presenting the potential for it to act as a S(IV) oxidant. Kinetic and mechanistic studies for the 03-S(IV) reaction in aqueous solutions have been reviewed and evaluated by Hoffmann (1986), who shows that it can be treated in terms of individual reactions of the various forms of S(IV) in solution. That is, S02 H20, HSOJ, and SO2- each react with 03 by unique mechanisms and with unique rate constants, although in all cases the reactions can be considered to be a nucleophilic attack by the sulfur species on 03. 

There are several types of environments on Earth where significant water exists at prevalent low temperatures such that ice and liquid aqueous solutions commonly coexist permafrost, snow, glaciers, lake and river ice, sea ice, and parts of the atmosphere (polar troposphere, global upper troposphere, and stratosphere). In addition, the deep sea floor occurs at temperatures very close to the freezing point of water. For example, temperatures in the oceanic abysses hover around 2°C at a maximum hydrostatic pressure of 1100 bars (10,660 m) in the Mariana Trench (Yayanos, 1995). Table 4.1 summarizes some of these environments. Furthermore, in some permafrost and sea-floor environments, the presence of nonpolar gases under pressure can stabilize a modified form of ice known as gas hydrates even where temperatures are not quite low enough for ordinary ice to form. 

Logan J.A., Nitrogen oxides in the troposphere Global and regional budgets. Advances in Chemistry, in press (1983). 

Logan, J. A. 1983. Nitrogen oxides in the troposphere global and regional budgets, f. Geopbys. Res. 88 10785-807. 

Clouds cover roughly two-thirds of our earth s surface and play an important role in influencing global climate by affecting the radiation budget. Cirrus clouds are one example of a cloud type whose optical properties are not accurately known. Cirrus clouds form in the upper troposphere and are composed almost exclusively of non-spherical ice crystal particles. The impact of cloud coverage on dispersion of pollution in the atmosphere is an area of great concern and intensive study. 

Fig. 4-13 Calculated and observed annual wet deposition of sulfur in mgS/m per year. (Reprinted from "Atmospheric Environment," Volume 30, Feichter, J., Kjellstrom, E., Rodhe, H., Dentener, F., Lelieveld, and Roelofs, G.-J., Simulation of the tropospheric sulfur cycle in a global climate model, pp. 1693-1707, Copyright 1996, with permission from Elsevier Science.)...

Cmtzen, P. J. (1988). Tropospheric ozone an overview. In "Tropospheric Ozone-Regional and Global Scale Interactions" (I. S. A. Isaksen, ed.). NATO ASI Series C, Vol. 227. D. Reidel Publ. Co., Boston, MA. 

Bergan, T., Gallardo, L. and Rodhe, H. (1999). Mercury in the global troposphere A three-dimensional study. Atmos. Environ. 33,1575-1585. 

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