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Trisaccharide Analogues

The 3H chemical shifts, coupling constants, temperature coefficients, exchange rates and inter-residual ROEs of the hydroxyl protons of various synthetic type II trisaccharides, analogues of (3-D-Galp-(l - 4)-p-D-GlcpNAc-(l - 2)-a-D-Man-(l - 0)(CH2)7CH3, were reported and interpreted,8 assisted with molecular dynamic simulations, to deduce key information on the conformational behavior of these important molecules in aqueous solution. [Pg.334]

The chitinase inhibitor allosamidine is a trisaccharide analogue with two N-acetylallosamine units bonded to a highly functionalized cyclopentano-oxazoline unit - allosamizoline. Analogues have now been described with one JV-acetylallo-samine unit, with the disaccharide bonded to an alternative hydroxyl of the cyclopentane, and thirdly with the oxazoline ring inverted. ... [Pg.66]

Figure 11.4 C,C-Trisaccharide analogue of type II O (H) blood group determinant. Figure 11.4 C,C-Trisaccharide analogue of type II O (H) blood group determinant.
SCHEME 16. A methyl glycoside analogue of a trisaccharide fragment found in E. coli. [Pg.51]

The trisaccharide a-Colp-(l->2)-(3-D-Gal -(l->3)-(3-D-GlcpNAc, a colitose analogue of the Lewisd (precursor) blood group antigen is part of the O-chain in the LPSs of Salmonella enterica serogroup 050.211 213... [Pg.182]

The conformational behavior of a C/O-analogue (55) of the Lewis X trisaccharide has also been thoroughly analyzed by off-resonance-ROESY NMR... [Pg.277]

Trisaccharides such as compound 64 featuring a 5-thiopyranosidic linkage were successfully synthesized with a view to sulfur-containing Lewis analogues [154]. [Pg.2014]


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Analogues of Trisaccharides

Analogues of Trisaccharides and Compounds with Anomalous Linking

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