Tris -diruthenium complexes

TRI-ju-CHLORO-CHLOROTETRAKIS(TRIPHENYLPHOS-PHINE)DIRUTHENIUM(II) COMPLEXES WITH ACETONE CARBONYL AND THIOCARBONYL LIGANDS... 

More recently, binuclear complexes derived from long-chain 3,4,5-trialkyloxybenzoates with chlorine were prepared ((98) M = Ru"/Ru , X = C1) and showed a low-temperature Colt phase, with in particular, room-temperature mesophases for the decyloxy and dodecyloxy homologs. Diruthenium(II,III) 3,4-di- 3,5-di- and 3,4,5-tri-(tetradecyloxy)benzoates also exhibited lyotropic mesophases in dodecane. They all behave similarly, in that the Colt phase is seen at concentrations below 40-55 wt.% of solvent. Above this concentration, and up to 60-70wt.% of solvent, the 3,5-di- and 3,4,5-trialkoxy compounds exhibited an additional CoIn phase. 

OC, Caiix>n monoxide (Continued) cobalt, iron, osmium, and mthenium complexes, 21 58-65 iron complex, 21 66, 68 manganese complexes, 23 34 molybdenum complexes, 23 4-9 niobium complexes, 23 34 palladium complex, 21 49 rhodium complexes, 23 124 ruthenium complex, 21 30 OCH4, Methanol, iridium complexes, 23 127 rhodium complexes, 23 127, 129 OCjlii, Acetone, compd. with carbonyltri-pi-chloTo-chlorotetrakis-(tri 4ienylpho phine)diruthenium (1 2), 21 30... 

The electrochemical behaviour and X-ray crystal structure of the unusual dimeric ruthenium(II) cyclooctadiene complex, [(tri-p-chloro)(chloro)(acetonitrile)bis(T -cyclooctadiene)diruthenium(II)] have been reported f . 

Self-assembly of a diruthenium precursor 285 as a bimetallic connector with tris-pyridyl ligand syntone 241 in the presence of silver(l) ions by Scheme 4.35 afforded a cationic TP (arene)ruthe-ninm Rne Ls La coordination capsule 540 [36]. This capsule encapsulates palladium and platinnm(ll) acetylacetonates to give the corresponding 1 1 cage complexes [36]. In the platinum-... 

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