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Trimethylsilyl trifluoromethane sulfonate

Di-0-dichloroacetyl-l-0-benzyloxycarbonyl-(4,6-0-ethylidene)-p-D-glucopyranose Palladium on carbon 4 -Demethyl-epi-podophyllotoxin Zinc acetate dihydrate Boron trifluoride etherate Trimethylsilyl trifluoromethane sulfonate Celite/basic alumina column... [Pg.1535]

The product from Step 5 (25 mol) was dissolved in CH2CI2 (90 kg), cooled to -30 to -20 °C, and borane-methyl sulfide (27.5 mol) and trimethylsilyl trifluoromethane-sulfonate (32.5 mol) added. After 1 hour, 10% aqueous NaHC03 (40 kg) was added, the mixture warmed to ambient temperature, stirred for 12 hours, and the isomers isolated in 90% yield. [Pg.30]

Treatment of 1,2-epoxycyclohexane with trimethylsilyl trifluoromethane-sulfonate in the presence of DBU in benzene at ambient temperature afforded 3-trimethylsilyloxycyclohexene (320) in 87% yield (81JAP(K)43289). [Pg.129]

N, N,N ,N -tetramethylethy lenediamine trimethylsilyl trifluoromethane sulfonate triphenylmethyl-borontetrafluoride... [Pg.609]

Dynasylan CT3610. See Trimethylsilyl iodide Dynasylan CT3650. See Trimethylsilyinitrile Dynasylan CT3795. See Trimethylsilyl trifluoromethane sulfonate Dynasylan CV4720. See... [Pg.1593]

Trifluoromethanesulfonic acid trimethylsilyl ester. See Trimethylsilyl trifluoromethane sulfonate... [Pg.4529]

Trimethyls lyl triflate. See Trimethylsilyl trifluoromethane sulfonate Trimethylsilyl trifluoromethane sulfonate CAS 27607-77-8 EINECS/ELINCS 248-565-4 Synonyms Trifluoromethanesulfonic acid trimethylsilyl ester Trimethylsilyl triflate Trimethylsilyl trifluoromethyl sulfonate Classification Silane Empirical C4HgF303SSi Formula CF3S03Si(CH3)3... [Pg.4576]

Thmethylsilyl thfluoromethyl sulfonate. See Trimethylsilyl trifluoromethane sulfonate Thmethylsilyl N-(trimethylsilyl) carbamate. See Bis (trimethylsilyl) carbamate a-(Trimethylsilyl)-uj-((trimethylsilyl) oxy). See Dimethylsiloxane... [Pg.4577]

Ferric chloride hexahydrate Iron pentacarbonyl Palladium diacetate Phosphotungstic acid Vanadium pentoxide catalyst, organic synthesis Boron tribromide Boron trichloride Boron trifluoride Cobalt Mercury acetate (ic) Trimethylsilyl trifluoromethane sulfonate Zinc acetate... [Pg.4942]

Trimethylsilyl iodide Trimethylsilyinitrile Trimethylsilyl trifluoromethane sulfonate Tripropylene glycol n-propyl ether Vinyidimethylchlorosilane Vinylmethyidichlorosilane Vinylmethyidiethoxysilane Vinyl methyidimethoxysilane Vinyltriethoxysilane Vinyltris (trimethylsiloxy) silane... [Pg.5031]

Stannous octoate Stearamide MEA Stearyl methacrylate 3-(N-Styrylmethyl-2-aminoethylamino) propyltrimethoxysilane hydrochloride Sucrose distearate Sulfated neatsfoot oil Sulfated olive oil Synthetic wax Talc Tall oil Tallowamide DEA Tallowamine acetate Tetra-n-butoxysilane Tetrakis (2-ethoxyethoxy) silane Tetrakis (2-methoxyethoxy) silane Tetramethoxysilane 2,2,4,4-TetramethyM, 3-cyclobutanediol 1,1,4,4-Tetramethyldichlorodisilethylene 1,1,3,3-Tetramethyldisiloxane Tetramethylsilane Tetramethylthiuram disulfide Tetra-n-propoxysilane Tributoxyethyl phosphate Tributyl phosphate Trichlorosilane Triethoxysilane N-[3-(Triethoxysilyl)-propyll 4,5-dihydroimidazole N-(Triethoxysilylpropyl) urea Triethylchlorosilane Triethyl phosphate Triethylsilane Trilauryl trithiophosphite Trilinoleic acid 1-Trimethoxysilyl-2-(chloromethyl) phenylethane Trimethoxysilylpropyidiethylene triamine N-Trimethoxysilylpropyl-N,N,N-trimethyl ammonium chloride Trimethylethoxysilane 2,6,8-Trimethylnonyl-4-alcohol Trimethylolpropane tricocoate 2,2,4-Tri methyl-1,3-pentanediol Trimethylsilyl acetamide o-Trimethylsilyl acetate Trimethylsilyl imidazole Trimethylsilyl iodide Trimethylsilyinitrile Trimethylsilyl trifluoromethane sulfonate Vermiculite Vinyidimethylchlorosilane ... [Pg.5431]

Trimethylsilyl trifluoromethane sulfonate Specialty Chemicals Source Book-Third Edition... [Pg.6500]

Silylation and Activation of Nucleobases. Base glycosi-dation, using the Vorbriiggen method. and its variations, has been a much exploited synthetic reaction in the formation of many important nucleoside analogs. BSA is used to activate the nucleobases by silylation. The persilylated nucleobases undergo nucleosidations with electrophiles in the presence of Lewis acids, generally tin(IV) chloride or trimethylsilyl trifluoromethane-sulfonate, while phenylselenenyl chloride, N-iodosuccinimide/triflic acid, and iodine have also been used to mediate these reactions. A typical nucleosidation reaction is shown in eq 27. Thymine 1 was treated with BSA in acetonitrile to form the silylated thymine 2 in situ, which is then reacted... [Pg.62]

See other pages where Trimethylsilyl trifluoromethane sulfonate is mentioned: [Pg.355]    [Pg.146]    [Pg.1536]    [Pg.113]    [Pg.24]    [Pg.82]    [Pg.272]    [Pg.396]    [Pg.40]    [Pg.248]    [Pg.635]    [Pg.635]    [Pg.651]    [Pg.524]    [Pg.525]    [Pg.528]    [Pg.530]    [Pg.531]    [Pg.533]    [Pg.537]    [Pg.538]    [Pg.539]    [Pg.541]    [Pg.542]    [Pg.4288]    [Pg.4914]    [Pg.5646]    [Pg.5646]    [Pg.6944]    [Pg.7033]    [Pg.155]    [Pg.544]    [Pg.155]   
See also in sourсe #XX -- [ Pg.544 ]



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