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1,3,5,2,4,6-Triazatriphosphorine

Die thermische Zersetzung von Diphenyl-thiophosphinsaure-methylamid bei 300—310° fiihrt zu 2,2,4,4,6,6-Hexaphenyl-1,3,5,2A5,4A3,6Xs-triazatriphosphorin (7%) als Hauptprodukt1132 ... [Pg.299]

Bis-[diphenyl-imino-phosphoranyl]-amin-Hydrochlorid reagiert mit zwei Hquivalenten Methanphosphonig-saure-dichlorid in siedendem Benzol zu einem Gemisch aus 6-Chlor-6-methyl-2,2,4,4-tetraphenyl-l, 3,5,22s, 42s,62s-triazatriphosphorin und Polymethyl-cyclopolyphosphan,l33 ... [Pg.299]

Hexachlor-l,3,5,2A5,4A5,6A5-triazatriphosphorin setzt sich mit Brenzcatechin bzw. 2-Amino-phenolen in Gegenwart von Triethylamin ebenfalls zu hexakoordinierten Phos-phoranat-Komplexen um2 7 ... [Pg.898]

Fluorinated compounds with P —F bonds react with Lewis acids. Thus, terr-butylpcntalluoro-SLibstituted triazatriphosphorines such as 1 are arylated in the presence of aluminum trichloride to form a new C —P bond. ... [Pg.662]

From the reaction of the sodium salt of an aliphatic or aromatic mercaptan (thiol) with hexachlorocyclotriphospha-zatriene (1,3,5,2,4,6-triazatriphosphorine 2,2,4,4,6,6-hexa-... [Pg.84]

For the first compound a solution of 13.3 g (0.036 mole) of 2,4,6-trichloro-2,4,6-tris(dimethylamino)-2,2,4,4,6,6-hexahydro-l,3,5,2,4,6-triazatriphosphorine in 150 mL of 1,2-dichloroethane, previously dried for 24 hours over CaS04, is stirred efficiently with a Teflon-bladed paddle stirrer in a250-mL, three-necked flask. The flask also carries a water-cooled condenser topped by a CaCl2 drying... [Pg.195]

A solution of 29,5 g (0.089 mole) of 2,2-dichloro-4,6-bis(dimethylamino)-4,6-difluoro-2,2,4,4,6,6-hexahydro-l,3,5,2,4,6-triazatriphosphorine in 200 mL of nitromethane, dried over CaS04, is refluxed with vigorous stirring for 20 hours with 40 g of a KSO2F/KF mixture. The solution is then filtered and the solvent is evaporated under reduced pressure. The residue is extracted with five 60-mL portions of petroleum ether (40-60° fraction) and the tetrafluorotriphos-phazene is obtained as a liquid by evaporation of the solvent. The yield is 20 g(75%). [Pg.197]

PENTACHLORO(VINYLOXY)CYCLOTRI-PHOSPHAZENES AND THEIR POLYMERS [2,2,4,4,6-Pentacliloro-6-(ethenyloxy)-l,3,5,2A, 4A, 6X > triazatriphosphorine]... [Pg.74]

See other pages where 1,3,5,2,4,6-Triazatriphosphorine is mentioned: [Pg.86]    [Pg.78]    [Pg.88]    [Pg.494]    [Pg.449]    [Pg.208]    [Pg.208]    [Pg.298]    [Pg.898]    [Pg.1135]    [Pg.1136]    [Pg.662]    [Pg.103]    [Pg.43]    [Pg.662]    [Pg.76]    [Pg.77]    [Pg.78]    [Pg.86]    [Pg.87]    [Pg.88]    [Pg.194]    [Pg.195]    [Pg.197]    [Pg.197]    [Pg.86]    [Pg.494]    [Pg.95]   


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1,3,6,2,4,6-Triazatriphosphorine 2,2,4,4,6,6-hexahydro

1,3,6,2,4,6-Triazatriphosphorine ethoxy and phenoxy derivatives

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