Transitions remotely connected

The correlation peaks in a basic homonuclear COSY experiment arise from both directly and remotely connected transitions and as such does not allow the measurement of coupling constants in complex spin systems [5.130, 5.134]. To try and rectify this problem the COSY45 experiment can be extended to include a DQF. In addition to... 

In order to connect remote energy resources new supply chains are needed. Quite often this implies the constructions of new main pipelines through transit countries, with increased reliability. The reliability of main pipelines is connected to various risks that may cause failure, or promote the termination of system functioning. The fundamentals among them are the following main risk elements ... 

In practice, the construction of function fi is connected with considerable limitations in the sphere of knowledge to which the subject of investigation refers. In the sphere of remote monitoring these limitations are explained by the presence of unsolved problems when optimizing the choice of the most informative wavelengths as well as by the absence of efficient methods to study non-stationary processes. Therefore, in the field of remote monitoring, both expert and empirical knowledge is combined at the level needed to study partial models for transition to a comparative analysis by criterion fi. 

The model just described accounts for the basic interactions needed in a cooperative transition but fails to include several factors. Correlations between base pairs more remote than nearest ones was not explicitly considered. Since we would expect the long-range correlations to damp out rapidly, this is probably not too important. Another factor that has been omitted in the previous model is the loop entropy. This is the configurational entropy which remains in unbonded strands after connecting bonds are broken. This entropy will depend on the size of the unbonded strands or loop and the flexibility of the DNA strands. 

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