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Transformed populations

Note that the deviation of the transformed population from 100% should not be understood as the error in our approximation (5.8). The integrated total transition probability according to (5.8) is V = 0.879, which is in excellent agreement with the value V = 0.864 obtained by numerical solution of (1.2). This deviation from 100% efficiency is intrinsic, i.e., it derives from the spread of the wavepacket. The total transition probability can be improved by increasing the laser intensity. This is because the range of A increases, as can be seen from (5.28). For instance, if we use I = 4.0TW/cm2, then the total transition probability reaches 93 94%. Since we have to be careful about multiphon processes, it is better not to use very high intensities. [Pg.107]

Alopaeus, V., Laakkonen, M. Aittamaa, J. 2006 Numerical solution of moment-transformed population balance equation with fixed quadrature points. Chemical Engineering Science 61, 4919-4929. [Pg.459]

Figure 8.3 Results of an 800 ha aerial spray trial against Oedaleus senegalensis, carried out in 1997 at Maine Soroa, eastern Niger (from Langewald el al., 1999). There were three pre-treatment sampling days bars are s.e. on means for back-transformed population counts... Figure 8.3 Results of an 800 ha aerial spray trial against Oedaleus senegalensis, carried out in 1997 at Maine Soroa, eastern Niger (from Langewald el al., 1999). There were three pre-treatment sampling days bars are s.e. on means for back-transformed population counts...
In the Lowdin approach to population analysis [Ldwdin 1970 Cusachs and Politzer 1968] the atomic orbitals are transformed to an orthogonal set, along with the molecular orbital coefficients. The transformed orbitals in the orthogonal set are given by ... [Pg.100]

The Lowdin population analysis scheme was created to circumvent some of the unreasonable orbital populations predicted by the Mulliken scheme, which it does. It is different in that the atomic orbitals are first transformed into an orthogonal set, and the molecular orbital coefficients are transformed to give the representation of the wave function in this new basis. This is less often used since it requires more computational work to complete the orthogonalization and has been incorporated into fewer software packages. The results are still basis-set-dependent. [Pg.100]

Degradation or Transformation. Degradation or transformation of a herbicide by soil microbes or by abiotic means has a significant influence not only on the herbicide s fate in the environment but also on the compound s efficacy. Herbicides that are readily degraded by soil microbes or other means may have a reduced environmental impact but may not be efficacious. Consider the phenomenon of herbicide-resistant soils. In these cases, repeated application of a given herbicide has led to a microbial population with an enhanced ability to degrade that herbicide (252,253). This results in a decrease or total loss of the ability of the herbicide to control the weed species in question in a cost-effective manner. [Pg.48]

The current needed for cathodic protection by impressed current is supplied from rectifier units. In Germany, the public electricity supply grid is so extensive that the CP transformer-rectifier (T-R) can be connected to it in most cases. Solar cells, thermogenerators or, for low protection currents, batteries, are only used as a source of current in exceptional cases (e.g., in sparsely populated areas) where there is no public electricity supply. Figure 8-1 shows the construction of a cathodic impressed current protection station for a pipeline. Housing, design and circuitry of the rectifier are described in this chapter. Chapter 7 gives information on impressed current anodes. [Pg.225]

The population of an antibonding orbital in the excited state allows the occurrence of chemical transformations that are electronically not available to ground-state species. [Pg.747]

General solution of the population balance is complex and normally requires numerical methods. Using the moment transformation of the population balance, however, it is possible to reduce the dimensionality of the population balance to that of the transport equations. It should also be noted, however, that although the mathematical effort to solve the population balance may therefore decrease considerably by use of a moment transformation, it always leads to a loss of information about the distribution of the variables with the particle size or any other internal co-ordinate. Full crystal size distribution (CSD) information can be recovered by numerical inversion of the leading moments (Pope, 1979 Randolph and Larson, 1988), but often just mean values suffice. [Pg.54]

The macromoment population balance ean be obtained from the maerodis-tributed population balanee (2.94). Making the transformation... [Pg.55]

The population balance in equation 2.86 employs the local instantaneous values of the velocity and concentration. In turbulent flow, there are fluctuations of the particle velocity as well as fluctuations of species and concentrations (Pope, 1979, 1985, 2000). Baldyga and Orciuch (1997, 2001) provide the appropriate generalization of the moment transformation equation 2.93 for the case of homogeneous and non-homogeneous turbulent particle flow by Reynolds averaging... [Pg.56]

More developed countries rely heavily on burning fossil fuels to meet energy needs. Fossil fuels are the remains of plants that, over millions of years, have been transformed into coal, petroleum, and natural gas. Just like the natural systems examined in this article, our energy ultimately comes from the Sun and photosynthesis. Although more developed countries have less than 20 percent of the world s population, they use more than 80 percent of the world s energy. [Pg.187]

In mathematics, Laplace s name is most often associated with the Laplace transform, a technique for solving differential equations. Laplace transforms are an often-used mathematical tool of engineers and scientists. In probability theory he invented many techniques for calculating the probabilities of events, and he applied them not only to the usual problems of games but also to problems of civic interest such as population statistics, mortality, and annuities, as well as testimony and verdicts. [Pg.702]

General Procedure Dose-response curves to a full agonist, before and after irreversible inactivation of a portion of the receptor population, are obtained in the same receptor preparation. It is essential that the same preparation be used as there can no differences in the stimulus-response coupling behavior of the preparation for both curves. From these dose-response curves, concentrations are calculated that produce the same response (equiactive concentrations). These are used in linear transformations to yield estimates of the affinity of the full agonist. [Pg.261]


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See also in sourсe #XX -- [ Pg.131 ]




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