Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Transformation invariant

The final rule follows from the transformational invariance of the mean squared end-to-end distance Flory exponent). As a hypothesis it is... [Pg.73]

To guarantee the transformational invariance of DG = kBT/(NQ (see Table 4) in the case of Rouse relaxation, the replacement of N by N/A, requires the simultaneous replacement of the segmental friction coefficient by X which is natural, since friction is proportional to the number of segments involved. [Pg.74]

Expressions (3.42) and (3.43) show that the Fourier transform of a direct-space spherical harmonic function is a reciprocal-space spherical harmonic function with the same /, in. This is summarized in the statement that the spherical harmonic functions are Fourier-transform invariant. It means, for example, that a dipolar density described by the function dl0, oriented along the c axis of a unit cell, will not contribute to the scattering of the (hkO) reflections, for which H is in the a b plane, which is a nodal plane of the function dU)((l, y). [Pg.69]

The t2g density is zero where two of the direction cosines x, y, and z are zero, that is, in the planes of the coordinate axes, but peaks along the eight cube diagonals. The density functions are Fourier-transform invariant, as discussed in chapter 3, and expressed by the equation... [Pg.262]

Paul Dirac used the Fock-Klein-Gordon equation to derive a Lorentz transformation invariant equation for a single fermion particle. The Dirac equation is solvable only for several very simple cases. One of them is the free particle (Dirac), and the other is an electron in the electrostatic field of a nucleus (Charles Darwin-but not the one you are thinking of). [Pg.124]

Breit constructed a many-electron relativistic theory that takes into aceount sueh a retarded potential in an approximate way. Breit explicitly considered only the electrons of an atom its nucleus (similar to the Dirac theory) created only an external field for the electrons. This ambitious project was only partly successful because the resulting theory turned out to be approximate not only from the point of view of quantum theory (wifli some interactions not taken into account), but also from the point of view of relativity theory (an approximate Lorentz transformation invariance). [Pg.146]

The ring-chain tautomerism between cyclobutene and butadiene is perhaps the most famUiar example of an allowed Woodward-Hoffmann process. This transformation invariably is discussed in every attempt to rationalize or teach the Woodward-Hoffmann orbital symmetry concepts. This popularity is due in large part to the existence of a geometrically well defined (and easily visualized) alternate, forbidden, electrocyclic pathway. Thus it is exceedingly simple to set up a nonaUowed strawman, the disrotatory ring opening, and... [Pg.714]


See other pages where Transformation invariant is mentioned: [Pg.450]    [Pg.460]    [Pg.74]    [Pg.72]    [Pg.98]    [Pg.557]    [Pg.567]    [Pg.121]    [Pg.2]    [Pg.250]    [Pg.320]    [Pg.78]    [Pg.557]    [Pg.567]    [Pg.1037]    [Pg.391]    [Pg.131]    [Pg.1037]   
See also in sourсe #XX -- [ Pg.504 ]




SEARCH



Gauge transformation invariance

Invariance under transformation

Invariance with respect to a unitary transformation

Martensitic transformations invariant plane

Martensitic transformations lattice invariant deformation

Numerical calculations transformational invariant

Scale-invariant feature transform

Spin-orbit coupling transformational invariant

Transformation of Lengths and Relativistic Invariants

Unitary transformation trace invariance

Unitary transformation, invariance

© 2024 chempedia.info