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Trans-gauche

With all-atom simulations the locations of the hydrogen atoms are known and so the order parameters can be calculated directly. Another structural property of interest is the ratio of trans conformations to gauche conformations for the CH2—CH2 bonds in the hydrocarbon tail. The trans gauche ratio can be estimated using a variety of experimental techniques such as Raman, infrared and NMR spectroscopy. [Pg.413]

R = -CH2CH(CH3)2, there occurs a modest deviation from a strict 0°-120° alternation which characterizes the trans-gauche sequence. This produces a helical structure with seven repeat units occurring in two turns. Even bulkier substituents, for example, o-methyl phenyl, produce still more open helices... [Pg.64]

Unlike other synthetic polymers, PVDF has a wealth of polymorphs at least four chain conformations are known and a fifth has been suggested (119). The four known distinct forms or phases are alpha (II), beta (I), gamma (III), and delta (IV). The most common a-phase is the trans-gauche (tgtg ) chain conformation placing hydrogen and fluorine atoms alternately on each side of the chain (120,121). It forms during polymerization and crystallizes from the melt at all temperatures (122,123). The other forms have also been well characterized (124—128). The density of the a polymorph crystals is 1.92 g/cm and that of the P polymorph crystals 1.97 g/cm (129) the density of amorphous PVDF is 1.68 g/cm (130). [Pg.387]

Looked at in a different way, the orientation of gauche conformations is always very low, and the oriented chains are predominantly in the trans conformation so that the increase in the trans/gauche ratio is accompanied by a rapid rise in trans orientation. In fact, it has been pointed out 27) that to a very good approximation the overall orientation... [Pg.105]

The phase transition of bilayer lipids is related to the highly ordered arrangement of the lipids inside the vesicle. In the ordered gel state below a characteristic temperature, the lipid hydrocarbon chains are in an all-trans configuration. When the temperature is increased, an endothermic phase transition occurs, during which there is a trans-gauche rotational isomerization along the chains which results in a lateral expansion and decrease in thickness of the bilayer. This so-called gel to liquid-crystalline transition has been demonstrated in many different lipid systems and the relationship of the transition to molecular structure and environmental conditions has been studied extensively. [Pg.294]

For poly(methylene), an exclusion distance (hard sphere diameter) of 2.00 A was used to prevent overlap of methylene residues. The calculation reproduced the accepted theoretical and experimental characteristic ratios (mean square unperturbed end-to-end distance relative to that for a freely jointed gaussian chain with the same number of segments) of 5.9. This wps for zero angular bias and a trans/gauche energy separation of 2.09 kJ mol". ... [Pg.284]

Figure 3. Average values of the z-component of the end-to-end distance as a function of angular bias, a, and trans/gauche energy separation ts.E. Figure 3. Average values of the z-component of the end-to-end distance as a function of angular bias, a, and trans/gauche energy separation ts.E.
It is possible to include in the above the effect of trans/ gauche energy difference, but this will entail conditional probability matrices of much greater complexity, leading to severe computational difficulties. [Pg.212]


See other pages where Trans-gauche is mentioned: [Pg.416]    [Pg.445]    [Pg.446]    [Pg.477]    [Pg.143]    [Pg.476]    [Pg.239]    [Pg.217]    [Pg.27]    [Pg.32]    [Pg.43]    [Pg.105]    [Pg.111]    [Pg.222]    [Pg.219]    [Pg.127]    [Pg.657]    [Pg.241]    [Pg.813]    [Pg.54]    [Pg.221]    [Pg.246]    [Pg.254]    [Pg.263]    [Pg.296]    [Pg.7]    [Pg.269]    [Pg.308]    [Pg.679]    [Pg.52]    [Pg.282]    [Pg.284]    [Pg.285]    [Pg.285]    [Pg.236]    [Pg.162]    [Pg.134]    [Pg.440]    [Pg.451]    [Pg.493]    [Pg.494]    [Pg.500]   


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Gauche

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