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Tracer-exchange positron-emission profiling

Maximum kinetic energy of positrons Temporal analysis of products tapered element oscillating mass balance tracer-exchange positron emission profiling unit cell... [Pg.279]

Figure 6 shows a schematic diagram of the reactor system used for tracer-exchange positron-emission profiling (TEX-PEP) experiments. During these tracer exchange experiments, a constant flow of unlabeled hydrocarbons in a hydrogen carrier stream is fed into the reactor. The -hexane/... [Pg.293]

E. J. M. Hensen, A. M. de Jong, and R. A. van Santen have written Chapter 7, which introduces the tracer exchange positron emission profiling (TEX-PEP) as an attractive technique for in-situ investigations, for example, in a stainless steel reactor, of the adsorption and diffusive properties of hydrocarbons in zeolites under chemical steady-state conditions. Self-diffusion coefficients of hydrocarbons, labeled by proton-emitting C at finite loadings and even in the presence of another imlabeled alkane, may be extracted. The method is illustrated by adsorption and diffusion measurements of linear (n-hexane) and branched (2-methylpentane) alkanes in Fl-ZSM-5 and silicalite-1. [Pg.413]


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