Titanium silicalite , transition metal

Key Words Lewis acid adducts, Radical oxidations, Epoxidation, Hydrogen peroxide, Bond dissociation energy, Catalyst durability, Methyltrioxorhenium, Cross-bridged cyclam, Mn(IV), Late transition metal. Propylene oxide. Titanium silicalite (TS-1) catalyst, Ethylanthrahydroquinone/H2 process, Polyoxometallates, Mn(IV) catalyst. Hydrogen abstraction. Rebound mechanism, Isotopic label, t-BuOOH, Peroxide adduct. 2008 Elsevier B.v. 

The subsequent Chapter 7 is devoted to the synthesis and characterization of molecular sieve materials containing transition metals in the framework. Authored by G. Perego, R. Millini and G. Bdlussi, this Chapter focuses on titanium-silicalite-1 which has recently been found to be a unique catalyst for selective oxidations with hydrogen peroxide. Also covered in this Chapter is the synthesis of vanadium- and iron-containing molecular sieves. 

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