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Through-space contact

Scheme 11 Potential competition of a direct close contact exchange path versus a through-space contact between large spin density sites. Scheme 11 Potential competition of a direct close contact exchange path versus a through-space contact between large spin density sites.
Table 5 Carbon-carbon intramolecular through space contact distance, (A), between overlapping carbons (see text for definition) and smallest contact distances for each molecule... Table 5 Carbon-carbon intramolecular through space contact distance, (A), between overlapping carbons (see text for definition) and smallest contact distances for each molecule...
A similar study of 4-methyl-4-benzoyl-N-methylpiperidine provided comparable results and the important conclusion that no charge-transfer quenching of the triplet ketone occurs as it does with acyclic y-amino ketones, proving that the charge transfer does not occur through bonds but requires close through space contact. ... [Pg.1164]

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See also in sourсe #XX -- [ Pg.129 ]



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Through-space

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