Three-state model, 112 stoichiometry

Three-state model, 1 1 1 Stoichiometry This simple sequential two-step unfolding reaction is described by the following equations... 

Three-state model, 1 1 2 Stoichiometry A very similar reaction scheme is presented in equation 61. The difference to the previous model is that here the intermediate occurs as dimer I2 and not as monomer I. 

Molecular modeling of aliphatic polyesters and polyamides suggested [61] that both classes of polymers may be capable of forming these IC s. For example, it was suggested that poly(e- caprolactone) (PEC) chains in either the all - trans or kink (g + tg+) conformations are slim enough to fit in these narrow IC channels (D = 5.5 A). Preliminary studies of its stability, stoichiometry, and structure, both the three - dimensional, solid - state structure of the PEC - U- IC and the conformation adopted by the included PEC chains have been reported [58],... 

---