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1,4-Thioxane

Borane—dimethyl sulfide complex (BMS) (2) is free of these inconveniences. The complex is a pure 1 1 adduct, ca 10 Af in BH, stable indefinitely at room temperature and soluble in ethers, dichioromethane, benzene, and other solvents (56,57). Its disadvantage is the unpleasant smell of dimethyl sulfide, which is volatile and water insoluble. Borane—1,4-thioxane complex (3), which is also a pure 1 1 adduct, ca 8 Af in BH, shows solubiUty characteristics similar to BMS (58). 1,4-Thioxane [15980-15-1] is slightly soluble in water and can be separated from the hydroboration products by extraction into water. [Pg.309]

The 4 1 complex has square planar coordination of platinum (Pt-S 2.317— 2.321 A) similar bond lengths are found in the corresponding complex with 1,4-thioxane [120]. Complexes with thiourea are important in Kurnakov s test (section 3.8.2) Pdtu4Cl2 has square planar coordination (Pd—S 2.33 A). [Pg.227]

Figure 9 Adducts of dimethylzinc with (a) trimethyltriazine (b) 1,4-dioxan (c) 1,4-thioxan. Figure 9 Adducts of dimethylzinc with (a) trimethyltriazine (b) 1,4-dioxan (c) 1,4-thioxan.
Oxidation of 1,4-thioxane by BTSP and f-butyl(trimethylsilyl) peroxide in CHCI3 at 25 °C is compared to those of the same substrate by the more common oxidants, f-butyl hydroperoxide and di-f-butyl peroxide, in the same solvent. The two silyl peroxides give similar oxidations rates, which are over 50 times higher than that measured for f-BuOOH, while f-Bu202 is almost unreactive under the conditions adopted. Oxidation... [Pg.805]

Thiophene, dioxirane oxidation, 1156 Thiourea, dialkyl peroxide synthesis, 706 1,4-Thioxane, oxidation, 805-6 Thiyl radicals, triplet oxygen domino reactions, 221-3, 224, 225, 226 THPO (1,2,3,4-tetrahydronaphthyl hydroperoxide), 331-2 Thromboxanes, from arachidonic hydroperoxides, 612... [Pg.1493]

Sulfur mustard-related compounds HOCH2CH2SCH2CH2OH H0CH2CH2S(0)CH2CH20H H0CH2CH2S(0)2CH2CH20H 0 TDG TDGO TDGO2 1,4-Thioxane 111-48-8 3085-45-8 2580-77-0 15980-15-1 24.25 24.25 24 24.25... [Pg.389]

Blister 2-Chloroethylethylsulfide, 1,4-thioxane, 1,4-dithiane, 2-mercaptoethanol, ethanol, benzene, toluene, xylene, chloroform... [Pg.819]

R = alkyl, aryl Ligand THF, Mo2S, 1,4-thioxane, diethylaniline R = H, alkyl... [Pg.100]

Oxathiane 1.4- Thioxane c4h8os 15980-15-1 Dechlorination of hemi-mustard, present in tonne containers... [Pg.113]

See other pages where 1,4-Thioxane is mentioned: [Pg.32]    [Pg.33]    [Pg.39]    [Pg.971]    [Pg.1015]    [Pg.621]    [Pg.226]    [Pg.348]    [Pg.373]    [Pg.365]    [Pg.1447]    [Pg.1145]    [Pg.122]    [Pg.369]    [Pg.153]    [Pg.12]    [Pg.130]    [Pg.397]    [Pg.294]    [Pg.163]    [Pg.1054]    [Pg.5208]    [Pg.820]    [Pg.214]    [Pg.621]    [Pg.621]    [Pg.201]    [Pg.204]    [Pg.207]    [Pg.25]    [Pg.80]    [Pg.511]    [Pg.68]    [Pg.264]    [Pg.264]   
See also in sourсe #XX -- [ Pg.23 , Pg.423 ]



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1,3-Thioxanes

1,3-Thioxanes

1,3-Thioxanes reduction

1,4-Thioxane, oxidation

Borane thioxane complex

Borane-1,4-thioxane

P Thioxane

Thioxane oxide

Thioxane oxide complexes

Thioxane ring

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