1,2,3,4-Tetrahydronaphthyl hydroperoxide

In 1996, Hamann and Hoft were able to obtain 1,2,3,4-tetrahydronaphthyl hydroperoxide (THPO, 16b) in enantiomerically enriched form starting from the racemic mixture by selective decomposition of one enantiomer in the presence of Jacobsen s catalyst 21 . Besides the enantiomerically enriched hydroperoxide (5)-16b, also the corresponding alcohol (/f)-l-tetralol (19b) was isolated in enantiomerically enriched form (opposite... [Pg.331]

Tetrahydronaphthyl hydroperoxide (THPO), kinetic resolution synthesis, 331-2... [Pg.1492]

Thiophene, dioxirane oxidation, 1156 Thiourea, dialkyl peroxide synthesis, 706 1,4-Thioxane, oxidation, 805-6 Thiyl radicals, triplet oxygen domino reactions, 221-3, 224, 225, 226 THPO (1,2,3,4-tetrahydronaphthyl hydroperoxide), 331-2 Thromboxanes, from arachidonic hydroperoxides, 612... [Pg.1493]

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