Thiotrithiazyl chloride

It detonates on percussion and decomposes rapidly above 90°C to give a residue, largely thiotrithiazyl chloride, which explodes above 170°C. 

Thiophosphoryl fluoride, 4340 Thiotrithiazyl chloride, 4033 Triboron pentafluoride, 0175... 

Tetratellurium tetranitride, 4773 Thiazyl fluoride, 4306 Thiotrithiazyl chloride, 4033 Thiotrithiazyl nitrate, 4767 Thiotrithiazyl perchlorate, 4032 2-Thioxo-4-thiazolidinone, 1112... 

The action of zinc dust on a suspension of thiotrithiazyl chloride, N3S4C1 (see p. 238), also gives the pentasulphide. 

With concentrated nitric acid, thiotrithiazyl chloride yields thiotrithiazyl nitrate, N3S4.NOa.7 Like nitrogen sulphide, with dilute aqueous alkali it yields sulphite and thiosulphate.8 When thiotrithiazyl chloride is boiled with alcohol and the resulting solution treated with a few drops of alcoholic potash, an intense violet-red coloration is produced. Ammonia gas is rapidly absorbed by the dry compound, which then explodes violently after a few minutes. If thiotrithiazyl chloride is suspended in chloroform and submitted to the action of a stream of ammonia gas, the liquid becomes orange-red ammonium chloride and ammonium sulphide are produced and nitrogen sulphide is regenerated.0... 

Thiotrithiazyl Iodide, N3S4I, may be prepared by dissolving thiotrithiazyl chloride in ice-cold water and adding excess of an ice-cold solution of potassium iodide. It is also formed by the action of iodine dissolved in methyl alcohol on thiotrithiazyl chloride, but prepared in this way it is invariably contaminated with chlorine. It is a dark red crystalline powder which decomposes spontaneously with evolution of iodine on exposure to air.3... 

Thiotrithiazyl Nitrate, N3S4NOa, may be obtained by dissolving thiotrithiazyl chloride in concentrated nitric acid and evaporating the yellow liquid produced in a vacuum. It forms long, yellow, transparent, prismatic crystals, which become opaque after several days and acquire the odour of sulphur dioxide and the oxides of nitrogen. It is explosive. Its solution in water is yellow at first, but quickly becomes... 

Thiotrithiazyl Hydrogen Sulphate, N3S4.HS04, is obtained when thiotrithiazyl chloride is dissolved in concentrated sulphuric acid. There is an evolution of hydrogen chloride and, on addition of acetic acid to the solution, the hydrogen sulphate is deposited as pale yellow needles.4... 

Thiotrithiazyl Thiocyanate, N3S4CNS, is obtained by adding a solution of potassium thiocyanate to an ice-cold solution of thiotrithiazyl chloride or nitrate. It forms lustrous bronze leaflets, readily soluble in benzene and chloroform. 

Thiotrithiazyl Chloride. (NS)3SC1 mw 205,72 N 20.43% yel solid mp, explds on heating, Sol in dil alkali acids such as sulfuric and nitric (with decompn) and w sol in coned mineral acids (without decompn) si sol in chlf insol in carbon... 

Thiotrithiazyl Nitrate (or Thionitrososulfomum nitrate). NS)3.S.N03 mw 232.28 N 24.13% long yel transparent prisms, becoming opaque on standing for several days after prepn. Sol in w with decompn as shown by the rapid change of the clear yel soln to opaque, and the pptn of a blk substance mixed with free S. Prepn is by dissolving Thiotrithiazyl Chloride in nitric acid and evapn of the solvent in vacuo. The refs... 

Thiophenol, see Benzenethiol, 2337 Thiophosphoryl chloride difluoride, 3974 Thiophosphoryl chloride, 4148 Thiophosphoryl fluoride, 4334 Thiotrithiazyl chloride, 4027 Thiotrithiazyl nitrate, 4762 Thiotrithiazyl perchlorate, 4026... 

Thiotrithiazyl chloride explodes when heated. Tetrasulfur tetranitride reacts with NOC1 in the following way to yield a product that contains the S3N2C1+ cation ... 

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