Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Thiophenes from thiazoles

T system, the PPP a—-tt method (133). The -tt and a net charges and bond orders of thiophene and thiazole are compared in Table 1-5. Whatever the method considered the variation of the indices occurs in the same sense when passing from thiophene to thiazole the replacement in the 3-position of a carbon atom by a nitrogen induces... [Pg.35]

It is difficult to draw general conclusions from such a small number of values. Nevertheless, it can be noted that, like other five- or six-membered unsaturated rings (thiophene, pyridine) thiazole exhibits a certain aromatic behavior in its magnetic susceptibility. [Pg.89]

A study of three commercially available extracts of yeast (Saccharomyces cerevisiae) identified 268 volatile components of which 67 contained sulfur (34 of these were identified for the first time as yeast extract components). The identified substances ranged from CS2 to complex thiophenes and thiazoles.28... [Pg.680]

Palladium chemistry involving heterocycles has its unique characteristics stemming from the heterocycles inherently different structural and electronic properties in comparison to the corresponding carbocyclic aryl compounds. One example illustrating the striking difference in reactivity between a heteroarene and a carbocyclic arene is the heteroaryl Heck reaction (vide infra, see Section 1.4). We define a heteroaryl Heck reaction as an intermolecular or an intramolecular Heck reaction occurring onto a heteroaryl recipient. Intermolecular Heck reactions of carbocyclic arenes as the recipients are rare [12a-d], whereas heterocycles including thiophenes, furans, thiazoles, oxazoles, imidazoles, pyrroles and indoles, etc. are excellent substrates. For instance, the heteroaryl Heck reaction of 2-chloro-3,6-diethylpyrazine (1) and benzoxazole occurred at the C(2) position of benzoxazole to elaborate pyrazinylbenzoxazole 2 [12e]. [Pg.1]

One active field of research involving the Heck reaction is asymmetric Heck reactions (AHR). The objective is to achieve enantiomerically-enriched Heck products from racemic substrates using a catalytic amount of chiral ligands, making the process more practical and economical Although intermolecular Heck reactions that occurred onto carbocyclic arenes are rare, they readily take place onto many heterocycles including thiophenes, furans, thiazoles, oxazoles,... [Pg.16]

Pyrazole-, Thiazole>, and Imidazole>fused Thiophens.—Starting from (410) and carrying out nucleophilic substitution with thioglycolate followed by ring-closure, as described for (384) and (408), the thieno[2,3-d]pyrazole system (411) was synthesized. Their ionization constants have been determined and the transmission of the influence of the substituents R has been studied and found to be more feeble than in naphthalene d benzo[b]thiophen. From the cyano-derivative (412), thiophen-fused derivatives such as (413) and (414) have been synthesized. Electrophilic... [Pg.471]

Chapter V. Quinaldine (V,2) 2-methyl-, 2 5-dimethyl- and 2-acetyl-thiophene (V,8-V,10) 2 5-dimethyl and 2 4-dimethyl-dicarbethoxy-p3nrole (V,12-V,13) 2-amino- and 2 4 dimethyl-thiazole (V,15-V,16) 3 5-dimethyl-pyrazole (V,17) 4-ethylp3rridine (from pyridine) (V,19) n-amyl-pyridines from picolines) (V,28) picolinic, nicotinic and isonicotinic acid (V,21-V,22) (ethyl nicotinate and p-cyanop3n idine (V,23-V,24) uramil (V,25) 4-methyl-(coumarin (V,28) 2-hyi-oxylepidine (V,29). [Pg.1191]

These results show that in the phenylation of thiazole with benzoyl peroxide two secondary reactions enter in competition the attack of thiazole by benzoyloxy radicals, leading to a mixture of thiazolyl benzoates, and the formation of dithiazolyle through attack of thiazole by the thiazolyl radicals resulting from hydrogen abstraction on the substrate and from the dimerization of these radicals. This last reaction is less important than in the case of thiophene but more important than in the case of pyridine (398). [Pg.109]

The one-electron reduction of thiazole in aqueous solution has been studied by the technique of pulse radiolysis and kinetic absorption spectrophotometry (514). The acetone ketyl radical (CH ljCOH and the solvated electron e were used as one-electron reducing agents. The reaction rate constant of with thiazole determined at pH 8.0 is fe = 2.1 X 10 mole sec in agreement with 2.5 x 10 mole sec" , the value given by the National Bureau of Standards (513). It is considerably higher than that for thiophene (6.5 x 10" mole" sec" ) (513) and pyrrole (6.0 X10 mole sec ) (513). The reaction rate constant of acetone ketyl radical with thiazolium ion determined at pH 0.8 is lc = 6.2=10 mole sec" . Relatively strong transient absorption spectra are observed from these one-electron reactions they show (nm) and e... [Pg.135]

The range of colours obtainable in monoazo dyes made by conpling representative derivatives of these amino heterocycles with para conpling tertiary amines is shown in Fignre 2.8. The diazo components from the thiazole and thiophene rings are especially important in the prodnction of bright bine azo dyes. ... [Pg.85]


See other pages where Thiophenes from thiazoles is mentioned: [Pg.122]    [Pg.874]    [Pg.454]    [Pg.224]    [Pg.415]    [Pg.747]    [Pg.278]    [Pg.343]    [Pg.122]    [Pg.874]    [Pg.310]    [Pg.282]    [Pg.122]    [Pg.343]    [Pg.454]    [Pg.874]    [Pg.901]    [Pg.874]    [Pg.851]    [Pg.479]    [Pg.516]    [Pg.58]    [Pg.154]    [Pg.78]    [Pg.750]    [Pg.33]    [Pg.67]    [Pg.8]    [Pg.312]    [Pg.385]    [Pg.99]    [Pg.17]    [Pg.177]    [Pg.265]    [Pg.278]   
See also in sourсe #XX -- [ Pg.340 ]




SEARCH



4- , from 4-thiazole

From Thiazoles

From thiophenes

© 2024 chempedia.info