Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Thioesters, reductive deoxygenation

Tri-/ -butyltin hydride also serves as a hydrogen-atom donor in radical-mediated methods for reductive deoxygenation of alcohols.131 The alcohol is converted to a thiocarbonyl derivative. These thioesters undergo a radical reaction with tri-w-butyltin... [Pg.290]

A new mild reaction for the deoxygenation of secondary alcohols has been applied successfully to sugars the reaction, which is radical in character, involves the reduction of a thiobenzoate with tributylstannane (see Scheme 25). Other references to the use of thioesters and the photochemical transformation of dithiobis(thioformates) into thiols are reported in Chapter II, the reaction of cyclic thiocarbonates with methyl iodide to give tu-iodo-iS-methyl thiocarbonates... [Pg.42]

See other pages where Thioesters, reductive deoxygenation is mentioned: [Pg.468]    [Pg.253]    [Pg.820]    [Pg.825]    [Pg.61]    [Pg.23]    [Pg.566]    [Pg.264]   
See also in sourсe #XX -- [ Pg.290 ]

See also in sourсe #XX -- [ Pg.290 ]



SEARCH



Reductive deoxygenation

Reductive deoxygenations

Thioester

Thioesters reduction

© 2024 chempedia.info