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Thiochloride

Hydrogen chloride adds to the P=N bond to give 3-chloro-dihydro-1,2,4,3-triazaphospholes (132) which may be converted to the thiochloride (133) (Scheme 42) (94HAC385). [Pg.805]

SbCls reacts with H2S forming antimony (V) thiochloride ... [Pg.51]

Preparation of Phosphorus Thiochloride. Put 33 ml of phosphorus trichloride and 12 g of finely triturated sulphur into flask 1 (Fig. 103). Place 3 g of anhydrous aluminium chloride into test tube 3. [Pg.162]

Pour the reaction mixture into the flask of an apparatus for fractional distillation under atmospheric pressure (see Fig. 20). Collect the fraction boiling at 125 °C. Pour the phosphorus thiochloride into a weighed drawn out test tube. Seal the ampoule wear eye protection ). Weigh the ampoule and the remaining parts of the test tube. Write the equation of the reaction. Calculate the yield in per cent. Test the reaction of phosphorus thiochloride with water. Write the equation of the reaction. What is the oxidation state of sulphur in this compound ... [Pg.162]

An alternative method is based on the interaction of mercuric chloride with polythionates in aqueous solution. A white precipitate of the mercuric thiochloride already mentioned under thiosulphuric acid 5 is formed the equation is... [Pg.223]

Arsenious oxide dissolves in the boiling trichloride to form arsenic oxychloride, AsOCl (seep. 109). Arsenic trisulphide yields thiochlorides.16... [Pg.107]

J. H. Gladstone and J. D. Holmes 1 agitated dil. aq. ammonia with thiophosphoryl chloride, and obtained an acid liquor which contained ammonium chloride and amidothiophosphoric acid, SP(NH2)(OH2), and from which the cadmium or lead salts could be precipitated, but not the salts of the alkaline earths, or of iron, nickel, or cobalt. Mercuric chloride gave a yellow thiochloride which became black when treated with acid. [Pg.725]

IDE PHOSPHOROUS SULFOCHLORIDE PHOSPHOROUS THIOCHLORIDE PHOSPHOROUS TRICHLORIDE SULFIDE SULFIDOTRICHLORID FOSFORECNY THIOCHLORID FOSFORECNY THIOPHOSPHORIC TRICHLORIDE THIOPHOSPHOR-YL TRICHLORIDE TL262 TRICHLOROPHOSPHINE SULFIDE... [Pg.1338]

GaCI3 gallium trichloride 13450-90-3 3.479 3398 PSCI3 phosphorus thiochloride 3982-91-0 3.634... [Pg.670]

PSC13 phosphorus thiochloride 3982-91-0 gas 1.420 1 4275 Si2C6H19N disilazane, hexamethyl 999-97-3 in benzene 0.420 1... [Pg.685]

See other pages where Thiochloride is mentioned: [Pg.103]    [Pg.451]    [Pg.206]    [Pg.218]    [Pg.224]    [Pg.290]    [Pg.161]    [Pg.172]    [Pg.190]    [Pg.202]    [Pg.259]    [Pg.119]    [Pg.628]    [Pg.161]    [Pg.411]    [Pg.411]    [Pg.206]    [Pg.108]    [Pg.725]    [Pg.1066]    [Pg.1068]    [Pg.1878]    [Pg.85]    [Pg.355]    [Pg.361]    [Pg.100]    [Pg.1841]    [Pg.1908]    [Pg.102]    [Pg.204]    [Pg.406]    [Pg.550]    [Pg.647]   
See also in sourсe #XX -- [ Pg.22 , Pg.176 , Pg.177 , Pg.186 , Pg.187 ]



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PHOSPHORUS THIOCHLORIDE

PSC13 PHOSPHORUS THIOCHLORIDE

Preparation of Phosphorus Thiochloride

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