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Thiocarbonyls, osmium

SC, Thiocarbonyls, osmium, 26 185-187 SC4Hb, Thiophene, tetrahydro-gold complexes, 26 85-87 SCjHj, 2,4-Pentadienthial osmium complex, 26 188 SC H6, Benzenethiol osmium complex, 26 304 SClF,0,PtCiiHio, Platinum(II), chloro-bis-(triethylphosphine)(trifluoromethane-sulfonato)-cis-, 26 126... [Pg.442]

CO 7Ru C,7. Ruthenium, fcarbido-hepta-decacarbonylhexa-, 26 281 CS, Thiocarbonyls, osmium, 26 185-187 CiHC1j02, Acetic acid, trichloro-, ruthenium complex, 26 256... [Pg.377]

B. DICHLORO(THIOCARBONYL)TRIS(TRIPHENYL-PHOSPHINE)OSMIUM(II)... [Pg.185]

Dichloro(thiocarbonyl)tris(triphenylphosphine)osmium(II) (2.0 g), triphenyl-phosphine (0.1 g) and sodium hydroxide (0.5 g) are combined with 2-methoxy-ethanol (20 mL) in a 100-mL flask, under a nitrogen atmosphere. The mixture is heated to reflux with stirring and maintained at reflux for 20 min. The resulting suspension is cooled on ice. Filtration gives white crystals, which are redissolved in dichloromethane and filtered through a Celite pad. Ethanol is added, and the dichloromethane is removed under reduced pressure. Filtration gives white crystals, which are washed with absolute ethanol (4 x 25 mL) and hexane (4 x 25 mL) and dried at room temperature. Yield 1.22-1.72g (65-91%). [Pg.186]

D. CARBONYL(THIOCARBONYL)TRIS(TRIPHENYL-PHOSPHINE)OSMIUM(O)6... [Pg.187]

H20 0s6Ci , Osmium, octadecacarbo-nyldihydridohexa-, 26 301 H2OsP,SCs,H4, Osmium(II), dihydrido-(thiocarbonyl)tris(triphenyl-phosphine)-, 26 186... [Pg.422]

G. R. Clark, K. Marsden, W. R. Roper, and L. J. Wright, Carbonyl, Thiocarbonyl, Selenocarbonyl, and Tellurocarbonyl Complexes Derived from a Dihalocarbene Complex of Osmium, J. Am. Chem. Soc. 102, 1206-1207 (1980). [Pg.291]

Roper and Town explain the conversion, with hydrogen, of an osmium-coordinated CS ligand in 94 to SMe in terms of successive hydride transfers from the metal to the thiocarbonyl ligand yielding first a thioformaldehyde complex and then a methanethiolate complex, 95 (95). Later this group... [Pg.26]

Little new chemistry of osmium thia-macrocycles has appeared, but both ruthenium and osmium [9]aneS3 complexes with thiocarbonyl ligands and their migratory coupling reactions have been investigated. ... [Pg.769]

See other pages where Thiocarbonyls, osmium is mentioned: [Pg.413]    [Pg.369]    [Pg.369]    [Pg.413]    [Pg.413]    [Pg.369]    [Pg.369]    [Pg.413]    [Pg.108]    [Pg.187]    [Pg.188]    [Pg.162]    [Pg.179]    [Pg.108]    [Pg.92]    [Pg.362]    [Pg.420]    [Pg.425]    [Pg.347]    [Pg.418]    [Pg.362]    [Pg.420]    [Pg.425]    [Pg.455]    [Pg.286]   
See also in sourсe #XX -- [ Pg.26 , Pg.185 ]

See also in sourсe #XX -- [ Pg.26 , Pg.185 ]



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