Osmium complexes thiocarbonyls

SC, Thiocarbonyls, osmium, 26 185-187 SC4Hb, Thiophene, tetrahydro-gold complexes, 26 85-87 SCjHj, 2,4-Pentadienthial osmium complex, 26 188 SC H6, Benzenethiol osmium complex, 26 304 SClF,0,PtCiiHio, Platinum(II), chloro-bis-(triethylphosphine)(trifluoromethane-sulfonato)-cis-, 26 126... 

G. R. Clark, K. Marsden, W. R. Roper, and L. J. Wright, Carbonyl, Thiocarbonyl, Selenocarbonyl, and Tellurocarbonyl Complexes Derived from a Dihalocarbene Complex of Osmium, J. Am. Chem. Soc. 102, 1206-1207 (1980). 

Roper and Town explain the conversion, with hydrogen, of an osmium-coordinated CS ligand in 94 to SMe in terms of successive hydride transfers from the metal to the thiocarbonyl ligand yielding first a thioformaldehyde complex and then a methanethiolate complex, 95 (95). Later this group... 

CO 7Ru C,7. Ruthenium, fcarbido-hepta-decacarbonylhexa-, 26 281 CS, Thiocarbonyls, osmium, 26 185-187 CiHC1j02, Acetic acid, trichloro-, ruthenium complex, 26 256... 

Little new chemistry of osmium thia-macrocycles has appeared, but both ruthenium and osmium [9]aneS3 complexes with thiocarbonyl ligands and their migratory coupling reactions have been investigated. ... 

Figure 5.2. Synthetic pathway for producing Os(CS)(CO)2(PPh3)3, a zerovaient osmium thiocarbonyl complex intended for use in novel oxidative addition reactions.

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