Thiabendazole, 2- 4-Thiazolyl benzimidazole

Thiabendazole Thiabendazole, 2-(4 -thiazolyl)benzimidazole (38.1.9), is also made in the same manner—heterocyclization which occurs upon reacting o-phenylendiamine with l,3-thiazol-4-carboxylic acid [4-6]. 

Application techniques can influence the efficacy of postharvest fungicides and, thus, alter the keeping quality of treated fruit. Application of sodium ortho-phenylphenate (SOPP) in a foam washer with an exposure time of only 15 to 20 sec is not as an effective method as a soak or drench treatment requiring 2-4 min (167). However, if proper pH control is not maintained, fruit may be burned with the soak or drench treatment (169, 170, 171). Applications of SOPP in wax were less phytotoxic (172). Within the last 14 years, development of the benzimidazoles, thiabendazole Q -(4 -thiazolyl) benzimidazole and. benoniyl Tmethyl 1-(butyl carbamoyl)-2-benzimidazole-carba-mat J, has led to the availability of fungicides with high... 

When the dihydro-1,2,4-triazinone (194) is heated at 180 °C under reducing conditions there is rupture of the 1,2-bond followed by ring closure, producing 4,5-diphenyl-imidazolinone (195). Such reductive ring closures of benzotriazine 1-oxides (196) can give benzimidazoles, in particular 2-(4-thiazolyl)benzimidazoles (197) ( thiabendazole ). Similar reactions take place with 1,3,5-triazines. In fact, primary amines cleave the compounds completely with evolution of ammonia and formation of iV.iV -disubstituted formamidines. With suitable primary amines, though, this reaction can be designed to produce imidazolines or benzimidazoles (Scheme 113). 

Examples of synthetically produced and biologically active benzimidazoles are the fungicides methyl l-butylcarbamoyl-2-benzimidazole carbamate (benomyl) 5 and 2-(4 -thiazolyl)benzimidazole (thiabendazole) 6. The latter is used extensively as a preservative for fruit (E 233) and as an anthelmintic in veterinary medicine ... 

Thiazolium, 3-methyl-2-((1-methyl-2-phenyl-1H-indol-3-yl) azo)-, chloride. See Basic red 29 2-Thiazolylamine. See 2-Aminothiazole, 2-(4-Thiazolyl) benzimidazole 2-(Thiazdl-4-yl) benzimidazole. See Thiabendazole 2-Thiazylamine. See 2-Aminothiazole Thieno (3,4-b)-1,4-dioxin, 2,3-dihydro. See 3,4-Ethylene dioxythiophene N-(2-Thienylcarbonyl)-L-methionine. See Thenoyl methionate 2-Thienyl mercaptan CAS 7774-74-5 FEMA 3062... 

Synonyms Apl-Luster Arbotect Bovizole Comfiival Eprofil Equizole Lombristop Mertec Mertect Mertect 160 Metasol TK-100 Mintesol Mintezol Minzolum MK 360 Mycozol Nemapan Omnizole Polival Storite TBDZ TBZ Tecto Tecto 60 Tecto RPH Thiaben Thiabendazol Thiabenzazole Thiabenzol 2-(Thiazol-4-yl)benzimidazole 2-(l,3-Thiazol-4-yl)benzimidazole 2-(4-Thiazolyl)benzimidazole 2-(4-Thiazolyl)-l/ -benzimidazole Thibenzol Thibenzole Thibenzole ATT Top Form Wormer. 

The fungicide 2-(4-thiazolyl)benzimidazole, known as thiabendazole (E233) has been used for the same purpose as biphenyl and o-phenylphenol and for the surface treatment of bananas. 

Thiabendazole Benzimidazole, 2-(4-thiazolyl)- (8) IH-Benzi-midazole, 2-(4-thiazolyl)- (9) (148-79-8)... 

SYNS APL-LUSTER ARBOTECT 4-(2-BENZI-MIDAZOLYL)THIAZOLE BOVIZOLE EPROFIL EQUIZOLE LOMBRISTOP MERTEC METASOL TK-100 MINTEZOL MINZOLUM MK 360 MYCOZOL NEMAPAN OMNIZOLE POLIVAL TBDZ TECTO THIABEN THIABENDAZOLE -(USDA) THIABENZOLE 2-(4-THIAZOLYL)-BENZIMDAZOLE 2-(4 -THIAZOLYL)BENZIMID-AZOLE 2-(4-THIAZOLYL)-lH-BENZIMIDAZOLE THIBENZOLE TOP FORM WORMER... 

Benzimidazole, 2-(4-thiazolyl)-, monophosphinate. See Thiabendazole hypophosphite salt... 

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