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Complexes thermodynamics of formation

Thermodynamics of complex formation between hard and soft acceptors and donors. S. Ahrland, Struct. Bonding (Berlin), 1968, 5,118-149 (103). [Pg.36]

Aegerter MA (1996) Sol-Gel Chromogenic Materials and Devices. 85 149-194 Ahrland S (1966) Factors Contributing to (b)-behavior in Acceptors. 1 207-220 Ahrland S (1968) Thermodynamics of Complex Formation between Hard and Soft Acceptors and Donors. 5 118-149... [Pg.241]

Ahrland, S. Thermodynamics of Complex Formation between Flard and Soft Acceptors and Donors. Vol. 5, pp. 118 149. [Pg.189]

Thermodynamics of complex formation of silver with several ligands such amines,368 hindered pyridine bases,369 nitrogen donor solvents,370 and azoles371 have been carried out. Other studies include the secondary-ion mass spectra of nonvolatile silver complexes,372 the relationship between Lewis acid-base behavior in the gas phase and the aqueous solution,373 or the rates of hydride abstraction from amines via reactions with ground-state Ag+.374... [Pg.927]

The kinetics and thermodynamics of complex formation in methanol for the interaction of cryptands 2.1.1,2.2.1 and 2.2.2 with the alkali metal... [Pg.206]

El Hage Chahine JM, Bauer AM, Baraldo K, Lion C, Ramiandrasoa F, Kunesch G. (2001) Kinetics and Thermodynamics of Complex Formation between Fe and Two Synthetic Chelators of the Dicatecholspermidine Family. Eur J Inorg Chem 2287... [Pg.59]

The thermodynamics of complex formation between the chelates ML2 (M = Zn or Hg HL = RC(SH)=CHCOCF3, R = Me or Ph) and py and bipy have been investigated.759 Zinc forms 1 1 complexes with both ligands, the bipy being bidentate. Mercury gives a 1 1 complex with py, but only an extremely unstable adduct is formed with bipy. [Pg.968]

See S. Ahrland, Enthalpy and Entropy Changes by Formation of Different Types of Complexes , Helv. Chim. Acta, 50, 306-318 (1967) and S. Ahrland, Thermodynamics of Complex Formation Between Hard and Soft Acceptors and Donors , in Structure and Bonding, Volume 5, C. K. Jorgensen, J. B. Neilands, R. S. Nyholm, D. Reinen, and R. J. P. Williams, eds, Springer-Verlag, New York, 1968, pp. 118-149. [Pg.211]

Thermodynamics of complex formation, discussed in detail by Schmidtchen in the present volume, hold many surprises.[32] In comparing enthalpic with entropic parameters one should not forget that AG and AS depend on the chosen units for relative concentration, which can be either mol/1, or can be given in dimensionless mole fractions in consequence the usual partition of absolute numbers for AH and AS becomes to some degree arbitrary (see e.g. ref. 2d, p. 24, p. 106). In addition, complexation is usually characterized by sizeable changes of heat capacity, making the thermodynamic partitions temperature-dependent. [Pg.282]

Other examples of various crown-ethers can be found in textbooks [4,5], monographs [563-568,571], and reviews [569,570,572], Different classifications are presented and fully examined [564,568], as well as their structures (for example, Refs. 568 and 573), thermodynamics of complex formation [574], and properties and applications [568,571],... [Pg.76]

Thermodynamics of complex-formation of alkali metal salts with crown ethers 91MI12. [Pg.340]

Thermodynamics of Complex Formation between Hard and Soft Acceptors and Donors... [Pg.118]

See other pages where Complexes thermodynamics of formation is mentioned: [Pg.945]    [Pg.169]    [Pg.173]    [Pg.205]    [Pg.220]    [Pg.936]    [Pg.937]    [Pg.140]    [Pg.456]    [Pg.133]    [Pg.136]    [Pg.441]    [Pg.8]   
See also in sourсe #XX -- [ Pg.299 , Pg.300 , Pg.301 , Pg.302 , Pg.303 ]

See also in sourсe #XX -- [ Pg.41 , Pg.131 ]

See also in sourсe #XX -- [ Pg.337 , Pg.338 ]

See also in sourсe #XX -- [ Pg.41 , Pg.131 ]



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