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Thermodynamic standard state unless otherwise specified

The thermodynamic standard state of a substance is its most stable pure form under standard pressure (one atmosphere) and at some specific temperature (25°C or 298 K unless otherwise specified). Examples of elements in their standard states at 25°C are hydrogen, gaseous diatomic molecules, H2(g) mercury, a silver-colored liquid metal,... [Pg.601]

Thermodynamic standard state of a substance The most stable state of the substance at one atmosphere pressure and at some specific temperature (25°C unless otherwise specified). [Pg.636]

The reference point for all enthalpy expressions is called the standard molar enthalpy of formation (AHf) which is defined as the heat change that results when 1 mole of a compound in its standard state is formed from its elements in their standard states. The standard state of a liquid or solid substance is its most thermodynamically stable pure form at 1 bar pressure. The standard state for gases is similar, except that standard state gases are assumed to obey the ideal gas law exactly. The standard state for solutes dissolved in solution will be discussed in Chapter 10. In the notation AHf, the superscript represents standard-state conditions (1 bar), and the subscript f stands for formation. Although the standard state does not specify a temperature, we will assume, unless otherwise stated, AH° values are measured at 25°C. [Pg.395]


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