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Thermodynamic control Kolbe-Schmitt reaction

The Kolbe-Schmitt reaction is an equilibrium process governed by thermodynamic control The position of equilibrium favors formation of the weaker base (salicylate ion) at the expense of the stronger one (phenoxide ion) Thermodynamic control is also responsible for the pronounced bias toward ortho over para substitution Salicylate anion IS a weaker base than p hydroxybenzoate and predominates at equilibrium... [Pg.1007]


See also in sourсe #XX -- [ Pg.1006 , Pg.1007 ]




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Control thermodynamics

Kolbe

Kolbe reaction

Kolbe-Schmitt reaction

Reactions thermodynamics

Schmitt

Schmitt reaction

Thermodynamic reaction control

Thermodynamic reactions

Thermodynamic-controlled reactions

Thermodynamically controlled

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