Thermodynamic Aspects of Chemical Conjugation

The kinetics and mechanisms of the majority of these reactions were also studied. It is shown that successful application of hydrogen peroxide is promoted by a combination of high induction properties and effectiveness and specificity of action in it, accompanied by the harmlessness of hydrogen peroxide dissociation products. 

hydrogen peroxide has found application in the implementation of the well-known organic reactions in the gas phase—dehydrogenation, epoxidation, hydrogenolysis, nitrile formation from /V-alkylbcnzcne, nitrogen fixation, etc. 

As mentioned in Chapter 2, there is the actual question about detection of a thermodynamic condition of conjugated oxidation of various substrates with hydrogen peroxide required for quantitative characterization of conjugation from the energy positions. For this purpose, let us show data on several non-spontaneous reactions, stimulated by chemical conjugation  

For reactions implemented with free energy increase the source of work is required. It is common knowledge that in the reaction system consisting of the overall reactions (4.2) and 

Conjugated Reactions of Oxidation with Hydrogen Peroxide in the Gas Phase 

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