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Thallium sulfate alkenes

Mercuric salts induce oxidative rearrangement of cyclic alkenes and give cycloalkane carboxaldehydes. Cyclohexene, for example, gave cyclopentane carboxaldehyde (404) in 53% yield. Acyclic alkenes such as 2-butene can also be oxidized with mercuric sulfate and sulfuric acid, giving 2-butanone in this case.566 Thallium nitrate [T1(N03)3] is an important reagent for the oxidative rearrangement of cyclic alkenes.567 The reaction is not restricted to carbocyclic compounds, but can also be applied to heterocyclic compounds as shown by the oxidation of 3,4-dihydro-277-pyran (405) to the dimethyl acetal (406) in 65% yield.568... [Pg.279]

See other pages where Thallium sulfate alkenes is mentioned: [Pg.1165]   
See also in sourсe #XX -- [ Pg.7 , Pg.447 ]

See also in sourсe #XX -- [ Pg.7 , Pg.447 ]

See also in sourсe #XX -- [ Pg.447 ]



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Thallium sulfate

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