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Thallium monoacetate

Thallium monoacetate, TIOCOCH3 (hygroscopic), behaves similarly to silver acetate or silver benzoate. In the presence of iodine, it accomplishes stereoselective hydroxylations of alkenes [410]. [Pg.17]

THALLIUM MONOACETATE or THALLOUS ACETATE (563-68-8) CjHjOj Tl Noncombustible solid. Moisture may cause decomposition. Solution is a mild base. Incompatible with strong acids, nitrates. Highly poisonous. [Pg.1001]

SYNONYMS Synonyms vary depending upon the specific soluble thallium compound, (thallium acetate) thallium (1) acetate, thallium monoacetate, thallous acetate, (thallium iodide) thallium (1) iodide, thallium monoiodide, thallous iodide... [Pg.948]

Thallium acetate Thallium (1+) acetate Thallium acetate (ous) Thallium monoacetate Thallous acetate... [Pg.4400]

Thallium (1+) chloride Thallium chloride (ous). See Thallium (I) chloride Thallium monoacetate. See Thallium (I) acetate Thallium monochloride. See Thallium (I) chloride... [Pg.4401]

Thallium trinitrate oxidi2es naphthols and hydroquinone monoethers, respectively, to quinones and 4,4-diaIkoxycyclohexa-2,5-dienones, eg, 4,4-dimethoxy-2-methyl-2,5-cyclohexadienone [57197-11 -2] (108) (111,112). The yield of (108) is 89%. Because the monoacetal is easily converted to the quinone, the yield of 5-hydroxy-l,4-naphthoquinone [481-39-0] is 64%. [Pg.417]

Thallium triacetate, TI(0C0CH3)3 1.5H20 (mp 182 C), like the monoacetate, is used for the stereoselective acetoxylation of alkenes [411] and for oxidations of alkenes to epoxides [412]. [Pg.17]

See other pages where Thallium monoacetate is mentioned: [Pg.1143]    [Pg.22]    [Pg.1143]    [Pg.22]    [Pg.1050]    [Pg.222]    [Pg.824]    [Pg.470]    [Pg.211]    [Pg.1165]    [Pg.173]   


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Monoacetalization

Monoacetate

Monoacetates

Monoacetic

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