Thallium III Chloride

Thalh-. thallic. thallium(III). -chlorat, n. tballic chlorate. thalliuin(III) chlorate, chlo-rid, n. thallic chloride. thallium(III) chloride, -ion, n thallic ion. thallium(III) ion. -oxyd,... 

The Teijin oxychlorination, on the other hand, is considered a modern version of the obsolete chlorohydrin process for the production of ethylene oxide. In this process, ethylene chlorohydrin is obtained by the catalytic reaction of ethylene with hydrochloric acid in presence of thallium(III) chloride catalyst ... 

Kovalente Halogenide werden von Halogenalanen hydriert. So liefert ihre Umsetzung mit Borfluorid Diboran nach (149) [220), wahrend die Hydrierung von InCl3 in Ather und in der Kalte nach (150) zu unlos-lichem Indiumalanat (226), mit Thallium (III )-chlorid in Ather unterhalb -95°C nach (151) zu Thalliumchloriddialanat (229) fiihren soli. Di-... 

Thallium(III) fluoride has been prepared by the action of fluorine or bromine trifluoride on thallium(III) oxide at 300°C. It is stable to ca 500°C but is extremely sensitive to moisture. Thallium(III) chloride can be obtained readily as the tetrahydrate [13453-33-3] by passing chlorine through a boiling suspension of HC1 in water. It can be dehydrated with thionyl chloride. Thallium(III) bromide tetrahydrate [13453-29-7] is prepared similarly, whereas the iodide prepared in this manner is thallium(I) triiodide [13453-37-7], H+Iy. 

Addition of CI2 to organogold(I) complexes has also been achieved by reaction with thallium(III) chloride [Eq. (47)] (13, 36, 180-182), the cis isomers being produced by this method. Reactions with X2 gave the trans isomers (179). 

Reactions of thallium(III) ions To study these reactions use a 0 2m solution of thallium(III) chloride, T1C13. 

Thallium(III) chloride reacts with 1,4,7-triazacyclononane and l,4,7-trimethyl-l,4,7-triazacyclo-nonane to produce 1 1 complexes. It is also possible to prepare the InBr3 adduct of 1,4,7-triazacyclononane. As noted earlier, the hydrolysis of this compound leads to the first well-authenticated In(III) /.t-hydroxo complex. 

Calculated and Experimental Stability Constants for Thallium(III) Chloride Complexes in Aqueous Solution at 25°C (in Molar Units)"... 

Relatively little work has been done on the redox reaction between thallium and halide/pseudohalide ions (75, 93, 97,110, 328-330). Let us consider the qualitative order of stability of thallium(III) in the form of TlXp " complexes, where X = Cl, Br, I, SCN, CN, Thallium(III) forms strong complexes with all these ligands on the other hand, it can oxidize the X ions to X2. It is well known that the thallium(III) chloride complexes are perfectly stable for an indefinite period of time. The corresponding bromide complexes are usually stable, but at low Br/Tl ratios Tl(III) can be reduced by Br the reduction is easily prevented by adding excess of bromine. The iodo and thiocyanato complexes are approximately equally unstable toward redox reaction Tl(III) is rapidly reduced by the anion.Finally, the cyano complexes... 

The stoichiometry determines the product. Thallium(III) chloride reacts similarly, but only the bis(organo)thallium chloride is formed. Thallium(III) chloride also reacts with... 

The stoichiometry determines the product. Thallium(III) chloride reacts similarly, but... 

Blewitt JP (1946) Radiation losses in the induction electron accelerator. Phys Rev 69, 87-95 Blixt J, Glaser J, Mink J, Persson I, Persson P, Sandstroem M (1995) Structure of thallium(III) chloride, bromide, and cyanide complexes in aqueous solution. J Am Chem Soc 117 5089-5104 Blonski S, Garofalini SH (1993) Molecular dynamics simulation of -alumina and y-alumina surfaces. Surf Sci 295 263-274... 

Thallium(III) chloride (0.2m). Dissolve 45.7g thallium(III) oxide, TI2O3, in 50ml of 6m hydrochloric acid. Evaporate the solution to dryness and dissolve the residue in water. Dilute the solution to 1 litre,... 

In this communication we will describe a reaction calorimeter developed by GERDING et al (1) and also give an example of its use for the study of the composition of the thallium(III)chloride and bromide complexes. 

Organolithium compounds are more reactive than Grignard reagents and in certain cases allow more complete substitution. For example, Grignard reagents substitute only two of the chlorine atoms in thallium(III) chloride when diethyl ether is the solvent, whereas lithium alkyls substitute all three ... 

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