Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Tetrafluoroethylene oxide decomposition

Hydroxymethylmethyldiazirine (209 unprotonated) formed propionaldehyde as the sole product by thermal nitrogen extrusion 4-hydroxy-l,2-diazaspiro[2.5]oct-l-ene (218) formed a mixture of cyclohexanone (73%), cyclohexenol (21%) and cyclohexene oxide (5%). Thermal decomposition of difluorodiazirine (219) was investigated intensively. In this case there is no intramolecular stabilization possible. On heating for three hours to 165-180 °C hexafluorocyclopropane and tetrafluoroethylene were formed together with perfluorofor-maldazine 64JHC59). [Pg.223]

The thermal stability of polytetrafluoroethylene oxide and PTFE have been compared under the same conditions by Donato et al. [263] between 450 and 600°C. The decomposition rate has a maximum at 628°C for the oxide and at 568°C for PTFE. The activation energy for the first-order degradations are 98 kcal mole"1 between 8.5 and 85% for the oxide polymer and 85 kcal mole-1 between 523 and 571°C for PTFE. The rate of weight loss is less than 1.2% per min for both polymers below T = 550°C for the oxide and T = 590°C for PTFE. The oxide, however, loses weight below 390° C whereas PTFE does not. The main components of the volatile material are trifluoroacetyl fluoride, carbonyl fluoride and tetrafluoroethylene. An end-initiated thermal degradation with small zip length is proposed. [Pg.125]

Billow and Miller [187] also reported fairly similar results for poly(phenylene)s prepared from mixtures of terphenyls. Poly(m-phenylene) [188], phenyl-substituted polyphenylene [189] and perfluoropolyphenylene [190] have thermal and oxidative stabilities similar to that of poly(p-phenylene). Polyphenylenes synthesized by Wurtz-Fittig and Ullmann reactions were reported to withstand heating up to 500°-550°C [187,191,192]. Electrically conductive azo derivatives of polyphenylene (cTo= l-40ohm cm ) were stable up to 300°C without any noticeable decomposition, whereas the conductive block co-polymer of poly-phenylene with p-diethynylbenezene could withstand heating for many hours at 400°-450°C [I], Poly(p-phenylene) as well as poly(tetrafluoroethylene) have been reported to withstand a similar temperature without any thermal degradation and may be used safely up to similar... [Pg.839]

CF2 CF2 < CF2 CF-CH CHMe < CF2 CF CH CH2 < CF2 CF-CF CF2 Approximate Arrhenius parameters have been obtained for the reaction of oxygen atoms ( F), from the mercury-sensitized decomposition of nitrous oxide, with the fluoroethylenes at two temperatures (25 and 150 °C) using the olefin CH2 C(CFs)Me as reference compound. All the fluoroethylenes appear less reactive than ethylene again with the exception of tetrafluoroethylene, reactivity being least for cis-l,2-di-fluoroethylene. The differences appear largely due to differences in activation energy, and the anomalous reactivity of tetrafluoroethylene is noteworthy. [Pg.54]

Perfluoropropene oxide is a convenient, volatile, thermal source of difluoro-carbene, and its use in the preparation of fluorocyclopropanes has been further exemplified, perfluorinated, polyfluorinated, and hydrocarbon olefins being employed as substrates (see also p. 17) it has also been employed to convert perfluorobut-2-yne into 3,3-difluoro-l,2-bis(trifluoromethyl)cyclo-propene. Qose examination of the reaction between the epoxide and a mixture of cis- and rra .r-l-chloro-l,2-difluoroethylene at ca. 200°C has revealed that stereospecific addition of difluorocarbene takes place, but that loss of configuration can subsequently result from slow thermal isomerization of the cyclopropane product. Thermal decomposition of perfluoropropene oxide at 200 "C in the absence of a trap yields mainly perfiuorocyclo-propane and trifluoroacetyl fluoride together with tetrafluoroethylene, perfluoroisobutene oxide, perfluorobut-l-ene, and poly(difluoromethylene). [Pg.146]


See other pages where Tetrafluoroethylene oxide decomposition is mentioned: [Pg.311]    [Pg.21]    [Pg.84]    [Pg.43]    [Pg.541]   
See also in sourсe #XX -- [ Pg.141 ]




SEARCH



Decomposition oxidant

Oxidation decomposition

Oxidative decomposition

Oxides, decompositions

Tetrafluoroethylene

Tetrafluoroethylene decomposition

Tetrafluoroethylene oxide

© 2024 chempedia.info