1-tert. Butylamino

A fascinating Ge complex has been made from 2-tert-butylamino-3-chloroqui-noxaline. ° ... 

Schwesingefs phosphazene base 2-tert-butylamino-2-diethylamino-l,3-dimethyl-perhydro-l,3,2-diazaphosphorine (PS-BEMP has a pKb = 27.5 in MeCN) has been immobilized and shown to have immense utility in the N- and O-alkylation of many weakly acidic heterocycles. Kim et al. has made extensive use of this reagent in the multi-step synthesis of a small collection of guanines possessing potential antiviral activity [90]. The generic procedure involved the direct alkylation of the purine moiety (20) (Scheme 2.64), promoted by PS-BEMP, resulting in a mixture... 

CASRN 5915-41-3 molecular formula C9H16CIN5 FW 229.71 ChemicaPPhysical The hydrolysis half-lives of terbuthylazin in O.lM-HCl, buffer at pH 5.0, and O.lM-NaOH solutions at 20 °C were 7.9, 86, and 12 d, respectively (Burkhard and Guth, 1981). Terbuthylazin degraded to 2-tert-butylamino-4-hydroxy-6-(ethylamino)-s-triazine. Under laboratory conditions, the half-lives of terbuthylazin in a Hatzenbiihl soil (pH 4.8) and Neuhofen soil (pH 6.5) at 22 °C were 84 and 170 d, respectively (Burkhard and Guth, 1981). 

Munder, B., Lidal, H., and Sandall, O.C. Physical solubility of hydrogen sulfide in aqueous solutions of 2-(tert-butylamino)ethanol, J. Chem. Eng. Data, 45(6) 1201-1204, 2000. 

Auch aus den Komponenten der Imin-Bildung (z.B. aus 2-Methyl-propanal und tert.-Butylamin) lassen sich durch Reaktion mit Cyan-trimethyl-silan 2-Amino-alkansaure-nitrile (z.B. 2-tert.-Butylamino-3-methyl-butansaure-nitril) herstellen1. 

C(CH,)3 C(CH,), C(CH,), CH3 C(CH3)3 2- tert.-Butylamino-l-( l,3-dithian-2-yl)- 3,3-dimethyl-Toxo-butan 3- ( 1-Adamantyl-amino) -4,4-dimelhyl-2- oxo-nentan 4- ( l-Adamantyl-aminoj-5,5-dimethv/-3- oxo-hexan 58 65 69... 

Chemical names original 2-methylthio-4,6-bis-ethyl amino-.v-triazine 2-tert-butylamino-4-ethylamino-6- m ct h () x y-.v-1 ri azi n c 2-chloro-4-ethylamino- 6-/crt-butylamino-.v-triazine... 

Chemical Name 5-(2-(tert-Butylamino)-l-hydroxyethyl)-m-phenylene bis(dimethylcarbamate)... 

Butylamino-2-cyclohexyl-vinyl)-diphenyl- E2, 67 [2-tert.-Butylamino-vinyl]-cthinyl-phenyl- E2, 68 Butyl-butyloxy- El, 406... 

Amino-1-butyloxy- IV/le, 172 2-tert.-Butylamino-l-hydroxy- E16d, 1124/1209 (Amin + Oxiran) E21e, 5376 (En + 0,0s = NR Red.)... 

Pentensaure 2-tert.-Butylamino-3-ethyl- -nitril E5, 1115 (2-C1—al-imin -I- KCN)... 

Furan 2-Amino-4-butylimino-5-ethyl-5-methyl-4,5-dihydro-E15/2, 1810 [R2C(OH)-C = C —CN + R-NH2] 2-Hexensaure 2-tert.-Butylamino-3-methoxy- -nitril E15/2, 1277 [R-CH(OR)2 + R-NC] 1,2,4-Oxadiazol 5-Methyl-3-octyl-E8c, 422 [H,7C8-C(NH2) = N-OH + (H3C-C0)20] 2-Pentensaure 2-tert.-Butylamino-3-meihoxy-4-methyl- -nitril E15/2, 1277 [R-CH(OR)2 + R-NC] Pyrrolidin (+ )-(5> I -Cyclopentyli-denamino-2-(methoxy-methyl)-E14b, 489 E21a, 997 (aus Keton)... 

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