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Tert-butyl peroxy

PEROXIDES AND PEROXIDE COMPOUNDS - ORGANIC PEROXIDES] (Vol 18) tert-Butyl peroxy-3,5,5trimethylhexanoate [13122-18-4]... [Pg.144]

ETHYL-3,3-DI(tert-BUTYL-PEROXY)BUTYRATE with at least 50% 2598 ... [Pg.221]

ETHYL-3,3-OI(tert-BUTYL-PEROXY)BUTYRATE, maximum concentration 2185 ... [Pg.221]

N-BUTYL-4,4-DI(tert-BUTYL-PEROXY) VALERATE (maxinun 52% 2141 995-33-5 ... [Pg.233]

Reaction between Grignard reagents and tert-butyl peroxy esters... [Pg.1669]

Peroxy ketals Butyl 4,4-bis (tert-butyl peroxy) valerate 143 160... [Pg.439]

Suitable inert solvents include methyl ethyl ketone, benzene, ethylbenzene and toluene. Suitable initiators include peresters and peroxycarbonates such as ferf-butyl perbenzoate, ferf-butyl peroxy isopropyl carbonate, fcrf-butyl peroctoate, tert-butyl peroxy isonon-... [Pg.217]

Dilauroyl peroxide, technically pure tert-Butyl peroxy-2-ethylhexanoate, 2124 900kPa400 at 400ms slowly propagating... [Pg.154]

The oxidized dimer, [Fe2(TPA)20(0Ac)]3+, 41, was shown to be an efficient catalyst for cyclohexane oxidation using tert-BuOOH as a source of oxygen (69). This catalyst reacts in CH3CN to yield cyclohexanol (9 equiv), cyclohexanone (11 equiv), and (tert-butylperoxy)cyclohexane (16 equiv) in 0.25 h at ambient temperatures and pressures under an inert atmosphere. The catalyst is not degraded during the catalytic reaction as determined by spectroscopic measurements and the fact that it can maintain its turnover efficiency with subsequent additions of oxidant. Solvent effects on product distribution were significant benzo-nitrile favored the hydroxylated products at the expense of (tert-butyl-peroxy)cyclohexane, whereas pyridine had the opposite effect. Addition of the two-electron oxidant trap, dimethyl sulfide, to the catalytic system completely suppressed the formation of cyclohexanol and cyclohexanone, but had no effect on the production of (tert-butylper-oxy)cyclohexane. These and other studies suggested that cyclohexanol and cyclohexanone must arise from an oxidant different from that responsible for the formation of (tert-butylperoxy)cyclohexane. Thus, two modes of tert-BuOOH decomposition were postulated a heterolytic... [Pg.123]

Butan 2-Brommercuri-l-tert.-butyl-peroxy-3-oxo- E13/1, 326 (Peroxymercurierung)... [Pg.534]

Cyclopentan l-Brom-2-tert.-butyl-peroxy- E13/1, 397 (HgBr -> Br) 1,3-Dioxan 2-(4-Brom-butyl)-5,5-dimethyl- E14a/1, 370 (Enol-ether 4- R—OH)... [Pg.667]

Carbamidsaure N-(2-Pyridylamino-sulfonyl)- -tert.-butyl-peroxy-ester El3/1, 281 (aus CI-S02-NCO)... [Pg.786]

Fumarsaure -allylester-tert.-butyl-peroxy ester E13/1, 797 (R-COOH - R-O-OH)... [Pg.916]

Bicyclo 2.2.1 [heptan 2-tert.-Butyl-peroxy-3-trifluoracetoxymercuri-E13/1, 323 (Peroxymercurierung)... [Pg.1173]

See other pages where Tert-butyl peroxy is mentioned: [Pg.213]    [Pg.248]    [Pg.248]    [Pg.248]    [Pg.248]    [Pg.56]    [Pg.694]    [Pg.439]    [Pg.6]    [Pg.13]    [Pg.269]    [Pg.275]    [Pg.160]    [Pg.168]    [Pg.56]    [Pg.147]    [Pg.145]    [Pg.145]    [Pg.247]    [Pg.213]    [Pg.248]    [Pg.248]    [Pg.248]    [Pg.248]    [Pg.6]    [Pg.557]    [Pg.1084]   
See also in sourсe #XX -- [ Pg.340 ]



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Tert-butyl peroxy-2-ethylhexanoate

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