Ternary reactions

Ternary Reactions among Polymer Substrates, Organohalogens, and Metal Oxides in the Condensed Phase under Pyrolytic Conditions... 

DREWS ETAL. Ternary Reactions under Pyrolytic Conditions... 

We now turn to reaction (8.14), the trapped plasmas combination reaction, in which the excess energy is removed by an extra positron as shown in Figure 8.9(c). The use of this ternary reaction for antihydrogen formation was first suggested by Gabrielse et al. (1988), who noted that its matter equivalent had been studied, mainly in relation to high temperature plasmas, for some time. These authors were therefore able to write the antihydrogen production rate, which corresponds to the recombination rate in conventional plasma physics, as... 

The ternary reactions (32) and (33) sequentially build up the NO+ hydrates until N0+(H20)3 is produced, which then undergoes a binary reaction to give the hydrated hydronium ions. Further increases in the size of the hydrates is considered to be via direct clustering ... 

The low recombination energy product ions can then undergo binary and ternary reactions which contribute to the establishment of a complex mixture of cluster ions. For example, subsequent to the production of NH3 by reaction (44), the fol-... 

At even higher temperatures, various binary and ternary reactions occur, but only a few, which occur in the metal-rich portion, will be mentioned here. The Y-phase still appears in its low-temperature 7-modification. On further heating ... 

The reactions in the Cu—W-S system, though similar, are simpler than those in the other systems above. For geologic reasons Moh66) has studied the system from near room temperature up to 900 °C. No ternary compounds were found. Thus, the phases which will enter into the ternary reactions are limited to the binaries. Copper and tungsten coexist at all temperatures and no binary alloys occur. 

Series of experiments were performed to outline the high-temperature phase relations of the X—Y phase solid solution series5, Fig. 25. Details of the individual ternary reactions have been discussed above. Both endmembers, the X-phase and the Y-phase, stable above 594 4 °C and 535 15 °C, respectively, form a complete solid solution series of pseudo-character, ie., at low temperatures Cu + MoS2 +... 

Secondary and ternary reactions proceed with different rates and yields. 

Primary reactions occur on the polymer that coats the bed particles. Secondary and ternary reactions occur in the gas inter-particles phase for a time that must be calculated as above cited. 

Butadiene yield increases if nitrogen is used instead of pyrolysis gas due to suppression of secondary and ternary reactions... 

One potential route around this problem is to infiltrate above the melting temperature of TiB, i.e., above 2190°C. In this case, the molten Ti will be in equilibrium with TiB2 and TiC, rather than TiB and TiC. The reaction conditions will then become similar to those in the Zr system. On cooling below 2190°C, though, the residual Ti in the composite should, at least thermodynamically, form TiB, according to a class II ternary reaction ... 

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