Template organic-inorganic

P. J. Hagrman, D. Hagrman, J. Zubieta, Organic-inorganic hybrid materials from simple coordination polymers to organodiamine-templated molybdenum oxides Angew. Chem., Int. Ed 1999, 38, 2639-2684, and references therein. 

Kagan CR, Breen T-L, Kosbar LL (2001) Patterning organic-inorganic thin-film transistors using microcontact printed templates. Appl Phys Lett 79 3536-3538... 

Polyacrylic acid Hybrid organic/inorganic network polymers were formed via the reaction of polyacrylic acid with tin(IV). titanium(IV), and silicon (IV) alkoxides and subsequent hydrolysis to form mesoporous materials. Treatment by nitric acid removed the polyacrylate template and produced microporous inorganic hydrous metal oxides Surface areas characterized by BET measurements 130... 

The high acidity of the unique sulfonic acid function of Nafion can also be utilized by tethering perfluoroalkanesulfonic acid groups to the surface of various silicas. Two approaches have been described to prepare such hybrid organic-inorganic materials. The grafted materials 3 have been prepared by reacting preformed silica materials (MCM-41, SBA-15) with sultone 2 [Eq. (2.31)].165 Co-condensation of tetraethoxy-silane with 4 in the presence of dodecylamine template, in turn, furnished the HMS-based material 5 [Eq. (2.32)].166,167... 

Mauritz, K.A., Organic-inorganic hybrid materials perfluorinated ionomers as sol-gel polymerization templates for inorganic alkoxides. Mater. Sci. Eng. C, 6, 121, 1998. 

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