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Temperature-Dependent Term of a Rate Equation

For many reactions, and particularly elementary reactions, the rate expression can be written as a product of a temperature-dependent term and a composition-dependent term, or [Pg.27]

For such reactions the temperature-dependent term, the reaction rate constant, has been found in practically all cases to be well represented by Arrhenius law  [Pg.27]

At the same concentration, but at two different temperatures, Arrhenius law indicates that [Pg.27]

But what moles are we referring to in the units of E This is unclear. However, since E and R always appear together, and since they both refer to the same number of moles, this bypasses the problem. This whole question can be avoided by using the ratio E/R throughout. [Pg.27]

This shows that Arrhenius law is a good approximation to the temperature dependency of both collision and transition-state theories. [Pg.28]


See other pages where Temperature-Dependent Term of a Rate Equation is mentioned: [Pg.27]    [Pg.27]   


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