Technetium, thiolate complexes

Technetium complexes with thioethers in the strict sense, i.e., those without other donor groups in the ligand molecule, comprise homoleptic thioether nitridotechnetium(V) complexes [111], cationic mixed thioether/thiolate complexes of Tc(III) [112], and a cationic Tc(I) complex [113]. However, these latter compounds do not properly fall within the scope of Tc(V) compounds and are excluded from review. 

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