Te group 14 element bond cleavage

Oxidative addition of other group 14 atom-tellurium bonds (Si-Te, Ge-Te, and Sn-Te) is also achieved (Eq. 3.47) [172]. Reactions of zero-valent platinum complex R(PEt3)3 with RTeMMcs (M = Se, Ge, Sn) at 25°C result in the formation of the tra 5 -Pt(TeR)(MMe2)(PEt3)2 within 10 min. 

N-0 bond in oxime Me2C=NOH can also be cleaved by reaction with tra 5-Re(Cl)(N2)(dppe)2 in the presence of TIBF4 to give tra 5-[Re(OH)(N= CMe2)(dppe)2][BE4] (Eq. 3.48) [173]. The rt-accepting ability of the N=CMe2 moiety may stabilize the product. 

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