Taper-shaped monoesters

Percec V, Heck J, Tomazos D, Falkenberg F, Blackwell H, Ungar G (1993) Self-assembly of taper-shaped monoesters of oligo(ethylene oxide) with 3,4,5-tris(p-dodecyloxybenzyloxy) benzoic acid and of their polymethacrylates into tubular supramolecular architectures displaying a columnar mesophase. J Chem Soe Ptakin Trans 1(22) 2799-2811. doi 10.1039/P19930002799... 

Their corresponding polymethacrylates (8) were obtained by free radical polymerization. These taper-shaped monoesters of oligo(ethylene oxide) (EO) with 3,4,5-tris(/ -dodecyloxybenzyloxy)benzoic acid and their corresponding polymers self-assembled into a tubular supramolecular architecture displaying an enantiotropic columnar hexagonal mesophase. This interesting supramolecular architecture is mentioned in the next section. 

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See also in sourсe #XX -- [ ]

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