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Tandem cyclization-anion capture

Grigg developed several palladium-catalyzed tandem cyclization-anion capture processes, and these include organoboron anion transfer agents [112, 164, 206]. Two examples of this methodology are shown. [Pg.106]

Queguiner made great use of Suzuki methodology to prepare heterobiaryls for use in carboline synthesis [169]. This chemistry is discussed in Chapter 4. As explored in more detail in Section 3.5, Grigg developed several Pd-catalyzed tandem cyclization-anion capture processes, and these include organoboron anion transfer agents [109, 170, 171], Two examples of this methodology are shown. [Pg.112]

Grigg and coworkers have used 2-tributylstannylfuran to terminate a variety of interesting tandem cyclization-anion capture reactions. In one example, aryl iodide 105 reacts via a 5-exo-trig process to provide dihydroindolone 106 [105-107]. [Pg.318]

Bicyclization-anion capture Strained bicyclic systems can be prepared by a tandem cyclization-anion capture process using a Pd catalyst in combination with sodium formate, tricthylaminc, or K2C02... [Pg.263]

RXN12 Tandem Cyclization-Anion-Capture Process ... [Pg.6]

RXN13 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Yne-Vinyl and ... [Pg.6]

RXN12 Tandem Cyclization-Anion-Capture Process of Ene-Vinyl, Ene-Aryl and Ene-Alkyl Halides... [Pg.95]

Nuss and co-workers have demonstrated that a tandem Heck cyclization-anion capture process can access substructures related to vitamin D [58] and the neocarzinostatin chromophore (162) (Scheme 6-28) [59]. In a one-pot procedure, diiodide 159 was converted into dienediyne 160 in low yield. In this reaction, the alkyne undergoes Heck... [Pg.408]

Z-tamoxifen 403 tandem cyclization 290, 295 tandem Heck reaction-anion capture 253-4 tandem Heck reaction-phenoxide capture 253 tandem Heck reactions 251, 252-4 tandem intramolecular Heck-intermolecular Stille cross-coupling 255 taxol 140, 143,243,245 ( )-tazettine 146,234 telomerization 352 telomerization products 343, 345 template effect 140 teraconic anhydride 468 terminal acetylenes, synthesis of 216-20 terminal alkynes 6, 213 terminal 2,2-diorgano-l-aIkcnylboronates 51 terminal diynes 207 ternary complex 444 ternary coupling 177... [Pg.269]

For previous reports of tandem Heck reaction-anionic capture sequences, see (a) Grigg, R., Sridharan, V. and Xu, L.-H. (1995) Palladium-catalyzed cyclization-amination of allenes - effect of base on regioselectivity of formation of allylic amines. J. Chem. Soc., Chem. Commun., 1903 and references cited therein (b) Ma, S. and Negishi, E. (1995) Palladium-catalyzed cyclization of general route to common, medium, and large ring compounds via cyclic carbopaUadation. J. Am. Chem. Soc., 117, 6345-7 and references cited therein. [Pg.565]


See other pages where Tandem cyclization-anion capture is mentioned: [Pg.262]    [Pg.262]    [Pg.185]    [Pg.380]    [Pg.49]    [Pg.49]    [Pg.49]   
See also in sourсe #XX -- [ Pg.318 ]




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RXN11 Tandem Cyclization-Anion Capture (-Carbonylation) Process of Alkenes, Allenes and Alkynes

Tandem cyclization

Tandem cyclization-capture

Tandem cyclizations

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