Synthetic Applications of Boron-Based MCRs

7 PALLADIUM-CATALYZED ASYMMETRIC ALLENE DmORATION/a-AMINOALLYLATION [Pg.143]

The synthesis of (-i-)-strictifolione 65 is accomplished in 5 synthetic steps with an overall yield of 23%. This synthesis demonstrates the utility of organoboron compounds to introduce the desired stereogenic center through a MCRs. [Pg.143]

SCHEME 4.29 Solid-phase synthesis approach with a supported aldehyde or the maleimide component. [Pg.144]

SCHEME 430 Palladium-catalyzed enantioselective diboration/allylation. [Pg.145]

Hall (Ed.), Boronic acids preparation and applications in organic synthesis and medicine, Wiley-VCH Verlag GmbH, Weinheim, Germany, 2005. [Pg.146]

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