Synthesis, Reactivity, and Structure

25 °C) selective lability of coordination sites in complexes of this inherently inert metal offers synthetic 

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Synthesis, reactivity, and structure of transition metal boryl compounds, derivatives of B,N- and B,0-heterocycles with B—M bond 98CRV2685. 

Maurya, M.R. 2003. Development of the coordination chemistry of vanadium through bis(acetylacetonato)oxovanadium(IV) Synthesis reactivity and structural aspects. Coord. Chem. Rev. 237 163-181. 

R. C. Larock, Organomercury Compounds in Organic Synthesis (Reactivity and Structure Concepts in Organic Chemistry), Vol. 22. Springer-Verlag, Berlin, 1985. 

Other compound classes, covered briefly in CHEC-II(1996), that stand out in this chapter are selenurane and tellurane dication salts, both in respect to synthesis, reactivity, and structural characterization. A review on the synthesis and properties of dichalcogena dications and trichalcogena hypervalent dications has been published <2000JOM116>. 

Weber, W.P. Gokel G.W. Phase Transfer Catalysis in Organic Synthesis Reactivity and Structure in Organic Chemistry 4 ... 

Veith M, Mathur S, Mathur C, Huch V. Synthesis, reactivity and structure of Hf-containmg homo and hetero-(bi- and tri-) metallic alkoxides based on edge-and face-sharing bioctahedral alkoxometalate ligands. J Chem Soc Dalton Trans 1997 2101-8. 

Library of Congress Cataloging in Publication Data. Birr, Chnstian, 1937- Aspects of the Mernfield peptides synthesis. (Reactivity and structure v. 8) Bibliography p. Includes index. 1. Peptide synthesis. I. Tide. II. Series. QD431.B57 54T.756 78-16659... 

Library of Congress Cataloging in Publication Data. Weber, William P 1940-. Phase transfer catalysis in organic synthesis. (Reactivity and structure v. 4) Includes bibliographies and indexes. 1. Catalysis. 2. Chemistry, Organic—Synthesis. I. Gokel, G. W., 1946- joint author. II. Title. III. Series. QD505.W4. 547.2. 77-22798... 

Bayer,M.J.,Piitzkow,H.,Siebert,W.2002.1,l,l-Trisborylalkanesasprecursorsfordicarbapentaboranes(5)-synthesis, reactivity, and structures of closo-l,5-bis(neopentyl)-2,3,4-trichloro-l,5-dicarbapentaborane and its derivatives. Eur. J. Inorg. Chem. 2002 1293-1300. 

Senge, M.O., Wiehe, A., and Ryppa, C., Synthesis, reactivity and structure of chlorophylls, in Biochemistry and Biophysics of Chlorophylls, Grimm, B., Porra, R., Rudiger, W., and Scheer, H., Eds., Kluwer, Dordrecht, in press. 

W. P. WF-BERandC. W. GOKEL, Phase Transfer Catalysis in Organic Synthesis, Vol. 4 of Reactivity and Structure, Springer-Verlag, 1977, 250 pp. C. M. Starks and C. Uotta, Phase Transfer Catalysis, Academic Press, New York, 1978, 365 pp. F. MontanaRI, D. Landini and F. Rolla, Topics in Current Chemistry 101, 149-201 (1982). E. V. Dehmlow and S. S. Dehmlow, Phase Transfer Catalysis (2nd edn.), VCH Publishers. London 1983, 386 pp. T. G. Southern, Polyhedron 8. 407-13 (1989). 

Razumov, A.I., Krasilnikova, E.A., Zykova, T.V., and Nevzorova, O.L., Reactivity and structure of phosphorylated carbonyl compounds. XVIII. Synthesis and investigation of the properties of [alkoxy(2-thienyl)phosphinyl]acetalde-hydes and their derivatives, J. Gen. Chem. U.S.S.R., 49, 469, 1979. 

W. P. Weber and G. W. Gokel, "Phase Transfer Catalysis in Organic Synthesis," in Reactivity and Structure. Vol. 4, K. Hafner et al., Eds., Springer-Verlag, Berlin - Heidelberg, 1977. 

This review has focused on the various methods that have been reported for the synthesis of metal nitride complexes, as well as even larger number of metal nitrides that have been isolated for a wide range of transition metals throughout the periodic table. It is clear that these complexes have an intriguing array of reactivity and structure. There is a burgeoning field of study that has demonstrated that these complexes already display a host of desirable properties in materials science, medicine, and chemical synthesis. Further investigations of the structure and reactivity of metal nitrides complexes will undoubtedly yield important contributions in the evolution of this exciting field. 

Blackborrow, J. R., Young, D. Reactivity and Structure in Organic Chemistry 9, Metal Vapour Synthesis in Organometallic Chemistry, Springer-Verlag, Berlin, Heidelberg, New York 1979... 

Synthesis, Reactivity, and Molecular Structure of Diphosphadisilacyclobutanes, Bis(stannyl)silyl-, and Bis(stannyl)germylphosphines... 

Jeske, G, Schock, L.E., Swepston, RN. et al. (1985) Highly reactive organolanthanides. Synthesis, chemistry, and structures of 4f hydrocarbyls and hydrides with chelating bis(polymethylcyclopentadienyl) Ugands. Journal of the American Chemical Society, 107, 8103. 

Jiang, G.F., Sun, J., and Shen, Y, Synthesis, reactivity and crystal structure of perfluoroalkylated diethoxyphosphinyl triphcnylphosphorane, J. Fluorine Chem.. 108, 207, 2001. 

To appreciate the wealth and diversity of crown ethers and their inclusion possibilities see for example Macrocyclic Poly ether Synthesis, G. W. Gokel and S. H. Korzeniowski, vol. 13 in Reactivity and structure concepts in organic chemistry, Springer-Verlag, Berlin, 1982. 

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